Slow magnetic relaxation in a high-spin pentacoordinate Fe(iii) complex

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Cyril Rajnák
  • Ján Titiš
  • Ján Moncoľ
  • Franz Renz
  • Roman Boča

Organisationseinheiten

Externe Organisationen

  • Slowakische Technische Universität Bratislava (STU)
  • Ss. Cyril and Methodius University
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Details

OriginalspracheEnglisch
Seiten (von - bis)13868-13871
Seitenumfang4
FachzeitschriftChemical Communications
Jahrgang55
Ausgabenummer92
PublikationsstatusVeröffentlicht - 31 Okt. 2019

Abstract

A mononuclear pentacoordinate iron(iii) complex shows slow magnetic relaxation with three relaxation channels. The high-frequency relaxation time of the order of microseconds is prolonged on cooling in accordance with the direct and Raman processes. The low frequency relaxation time is little dependent on temperature and varies in the range τ(LF) = 0.52-0.79 s.

ASJC Scopus Sachgebiete

Zitieren

Slow magnetic relaxation in a high-spin pentacoordinate Fe(iii) complex. / Rajnák, Cyril; Titiš, Ján; Moncoľ, Ján et al.
in: Chemical Communications, Jahrgang 55, Nr. 92, 31.10.2019, S. 13868-13871.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Rajnák, C, Titiš, J, Moncoľ, J, Renz, F & Boča, R 2019, 'Slow magnetic relaxation in a high-spin pentacoordinate Fe(iii) complex', Chemical Communications, Jg. 55, Nr. 92, S. 13868-13871. https://doi.org/10.1039/c9cc06610a
Rajnák, C., Titiš, J., Moncoľ, J., Renz, F., & Boča, R. (2019). Slow magnetic relaxation in a high-spin pentacoordinate Fe(iii) complex. Chemical Communications, 55(92), 13868-13871. https://doi.org/10.1039/c9cc06610a
Rajnák C, Titiš J, Moncoľ J, Renz F, Boča R. Slow magnetic relaxation in a high-spin pentacoordinate Fe(iii) complex. Chemical Communications. 2019 Okt 31;55(92):13868-13871. doi: 10.1039/c9cc06610a
Rajnák, Cyril ; Titiš, Ján ; Moncoľ, Ján et al. / Slow magnetic relaxation in a high-spin pentacoordinate Fe(iii) complex. in: Chemical Communications. 2019 ; Jahrgang 55, Nr. 92. S. 13868-13871.
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AU - Rajnák, Cyril

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AU - Moncoľ, Ján

AU - Renz, Franz

AU - Boča, Roman

N1 - Funding information: Slovak grant agencies (APVV 16-0039, APVV 18-0016, VEGA 1/ 0919/17 and VEGA 1/0013/18) along with the DAAD(D/SK) project are acknowledged for the financial support. Also, the projects NFP313010V954 of call OPVaI-VA/DP/2018/1.1.3-07 and ITMS 26240220084 cofounded by the European Regional Development Fund are acknowledged.

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AB - A mononuclear pentacoordinate iron(iii) complex shows slow magnetic relaxation with three relaxation channels. The high-frequency relaxation time of the order of microseconds is prolonged on cooling in accordance with the direct and Raman processes. The low frequency relaxation time is little dependent on temperature and varies in the range τ(LF) = 0.52-0.79 s.

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