Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 2863-2867 |
| Seitenumfang | 5 |
| Fachzeitschrift | Journal of Physical Chemistry A |
| Jahrgang | 120 |
| Ausgabenummer | 18 |
| Frühes Online-Datum | 29 Apr. 2016 |
| Publikationsstatus | Veröffentlicht - 12 Mai 2016 |
Abstract
Formic acid and dimethyl ether are combined in a supersonic expansion to form a molecular adduct with the two subunits held together by a "classical" OH⋯O hydrogen bond and a bifurcated weak CH2⋯O hydrogen bond. The rotational spectra of the parent and of two 13C isotopologues in natural abundance show that the complex has Cs symmetry, with the heavy atom symmetry planes of HCOOH and (CH3)2O perpendicular to each other.
ASJC Scopus Sachgebiete
- Chemie (insg.)
- Physikalische und Theoretische Chemie
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in: Journal of Physical Chemistry A, Jahrgang 120, Nr. 18, 12.05.2016, S. 2863-2867.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Shape of the Adduct Formic Acid-Dimethyl Ether
T2 - A Rotational Study
AU - Evangelisti, Luca
AU - Spada, Lorenzo
AU - Li, Weixing
AU - Ciurlini, Anna
AU - Grabow, Jens Uwe
AU - Caminati, Walther
N1 - Funding information: We thank the Italian MIUR (PRIN project 2010ERFKXL-001) and the University of Bologna (RFO) for financial support. L.E. was supported by Marie Curie fellowship PIOF-GA-2012- 328405. W.L. thanks the China Scholarships Council (CSC) for financial support. J.-U.G thanks the Deutsche Forschungsgemeinschaft (DFG) and the Land Niedersachsen.
PY - 2016/5/12
Y1 - 2016/5/12
N2 - Formic acid and dimethyl ether are combined in a supersonic expansion to form a molecular adduct with the two subunits held together by a "classical" OH⋯O hydrogen bond and a bifurcated weak CH2⋯O hydrogen bond. The rotational spectra of the parent and of two 13C isotopologues in natural abundance show that the complex has Cs symmetry, with the heavy atom symmetry planes of HCOOH and (CH3)2O perpendicular to each other.
AB - Formic acid and dimethyl ether are combined in a supersonic expansion to form a molecular adduct with the two subunits held together by a "classical" OH⋯O hydrogen bond and a bifurcated weak CH2⋯O hydrogen bond. The rotational spectra of the parent and of two 13C isotopologues in natural abundance show that the complex has Cs symmetry, with the heavy atom symmetry planes of HCOOH and (CH3)2O perpendicular to each other.
UR - http://www.scopus.com/inward/record.url?scp=84969800760&partnerID=8YFLogxK
U2 - 10.1021/acs.jpca.6b02912
DO - 10.1021/acs.jpca.6b02912
M3 - Article
AN - SCOPUS:84969800760
VL - 120
SP - 2863
EP - 2867
JO - Journal of Physical Chemistry A
JF - Journal of Physical Chemistry A
SN - 1089-5639
IS - 18
ER -