Robust Superhydrophobic/Superoleophilic Wrinkled Microspherical MOF@rGO Composites for Efficient Oil–Water Separation

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Jiahui Gu
  • Hongwei Fan
  • Chunxi Li
  • Jürgen Caro
  • Hong Meng

Externe Organisationen

  • Beijing University of Chemical Technology
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)5297-5301
Seitenumfang5
FachzeitschriftAngewandte Chemie - International Edition
Jahrgang58
Ausgabenummer16
Frühes Online-Datum1 Apr. 2019
PublikationsstatusVeröffentlicht - 8 Apr. 2019

Abstract

Graphene/MOF-based composite materials in three-dimensional (3D) architectures are promising for the treatment of oil-containing wastewater by absorption owing to their intrinsic properties of graphene and metal-organic frameworks (MOFs), such as high porosity, ultralow density, and facilely tailored superwettability. In this study, novel wrinkled 3D microspherical MOF@rGO composites with both superhydrophobic and superoleophilic properties were developed by embedding MOF nanoparticles between graphene oxide (GO) nanosheets, followed by high-temperature reduction self-assembly. The microspherical composites feature a unique micro/nano hierarchy consisting of crumpled reduced GO (rGO) nanosheets intercalated with well-dispersed MOF nanoparticles. Combined with the superwettability and abundant meso/microporosity, the peculiar architectures of wrinkled ZIF-8@rGO microspheres show very fast absorption rates and high sorption selectivity for organic solvents and oils from water.

ASJC Scopus Sachgebiete

Zitieren

Robust Superhydrophobic/Superoleophilic Wrinkled Microspherical MOF@rGO Composites for Efficient Oil–Water Separation. / Gu, Jiahui; Fan, Hongwei; Li, Chunxi et al.
in: Angewandte Chemie - International Edition, Jahrgang 58, Nr. 16, 08.04.2019, S. 5297-5301.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Gu J, Fan H, Li C, Caro J, Meng H. Robust Superhydrophobic/Superoleophilic Wrinkled Microspherical MOF@rGO Composites for Efficient Oil–Water Separation. Angewandte Chemie - International Edition. 2019 Apr 8;58(16):5297-5301. Epub 2019 Apr 1. doi: 10.1002/ange.201814487, 10.1002/anie.201814487
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abstract = "Graphene/MOF-based composite materials in three-dimensional (3D) architectures are promising for the treatment of oil-containing wastewater by absorption owing to their intrinsic properties of graphene and metal-organic frameworks (MOFs), such as high porosity, ultralow density, and facilely tailored superwettability. In this study, novel wrinkled 3D microspherical MOF@rGO composites with both superhydrophobic and superoleophilic properties were developed by embedding MOF nanoparticles between graphene oxide (GO) nanosheets, followed by high-temperature reduction self-assembly. The microspherical composites feature a unique micro/nano hierarchy consisting of crumpled reduced GO (rGO) nanosheets intercalated with well-dispersed MOF nanoparticles. Combined with the superwettability and abundant meso/microporosity, the peculiar architectures of wrinkled ZIF-8@rGO microspheres show very fast absorption rates and high sorption selectivity for organic solvents and oils from water.",
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AU - Gu, Jiahui

AU - Fan, Hongwei

AU - Li, Chunxi

AU - Caro, Jürgen

AU - Meng, Hong

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Y1 - 2019/4/8

N2 - Graphene/MOF-based composite materials in three-dimensional (3D) architectures are promising for the treatment of oil-containing wastewater by absorption owing to their intrinsic properties of graphene and metal-organic frameworks (MOFs), such as high porosity, ultralow density, and facilely tailored superwettability. In this study, novel wrinkled 3D microspherical MOF@rGO composites with both superhydrophobic and superoleophilic properties were developed by embedding MOF nanoparticles between graphene oxide (GO) nanosheets, followed by high-temperature reduction self-assembly. The microspherical composites feature a unique micro/nano hierarchy consisting of crumpled reduced GO (rGO) nanosheets intercalated with well-dispersed MOF nanoparticles. Combined with the superwettability and abundant meso/microporosity, the peculiar architectures of wrinkled ZIF-8@rGO microspheres show very fast absorption rates and high sorption selectivity for organic solvents and oils from water.

AB - Graphene/MOF-based composite materials in three-dimensional (3D) architectures are promising for the treatment of oil-containing wastewater by absorption owing to their intrinsic properties of graphene and metal-organic frameworks (MOFs), such as high porosity, ultralow density, and facilely tailored superwettability. In this study, novel wrinkled 3D microspherical MOF@rGO composites with both superhydrophobic and superoleophilic properties were developed by embedding MOF nanoparticles between graphene oxide (GO) nanosheets, followed by high-temperature reduction self-assembly. The microspherical composites feature a unique micro/nano hierarchy consisting of crumpled reduced GO (rGO) nanosheets intercalated with well-dispersed MOF nanoparticles. Combined with the superwettability and abundant meso/microporosity, the peculiar architectures of wrinkled ZIF-8@rGO microspheres show very fast absorption rates and high sorption selectivity for organic solvents and oils from water.

KW - graphene-based microspheres

KW - metal–organic frameworks

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KW - superoleophilicity

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