Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 4281-4284 |
| Seitenumfang | 4 |
| Fachzeitschrift | Tetrahedron Letters |
| Jahrgang | 29 |
| Ausgabenummer | 34 |
| Publikationsstatus | Veröffentlicht - 1988 |
| Extern publiziert | Ja |
Abstract
Lithiated allylsilanes 1 undergo smooth addition to epoxides 4 with variable α, γ regioselectivity yielding the C-silylated enols 5,7 and 6,8, respectively. γ-Selectivity can be successfully enhanced by use of cuprates.
ASJC Scopus Sachgebiete
- Biochemie, Genetik und Molekularbiologie (insg.)
- Biochemie
- Pharmakologie, Toxikologie und Pharmazie (insg.)
- Wirkstoffforschung
- Chemie (insg.)
- Organische Chemie
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in: Tetrahedron Letters, Jahrgang 29, Nr. 34, 1988, S. 4281-4284.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Ring-opening of oxiranes by silyl-substituted allyl anions. A regiochemical chameleon
AU - Schaumann, Ernst
AU - Kirschning, Andreas
PY - 1988
Y1 - 1988
N2 - Lithiated allylsilanes 1 undergo smooth addition to epoxides 4 with variable α, γ regioselectivity yielding the C-silylated enols 5,7 and 6,8, respectively. γ-Selectivity can be successfully enhanced by use of cuprates.
AB - Lithiated allylsilanes 1 undergo smooth addition to epoxides 4 with variable α, γ regioselectivity yielding the C-silylated enols 5,7 and 6,8, respectively. γ-Selectivity can be successfully enhanced by use of cuprates.
UR - http://www.scopus.com/inward/record.url?scp=0000991923&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(00)80474-8
DO - 10.1016/S0040-4039(00)80474-8
M3 - Article
AN - SCOPUS:0000991923
VL - 29
SP - 4281
EP - 4284
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 34
ER -