Recombination activity of interstitial chromium and chromium-boron pairs in silicon

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Jan Schmidt
  • Rafael Krain
  • Karsten Bothe
  • Gerhard Pensl
  • Svetlana Beljakowa

Externe Organisationen

  • Institut für Solarenergieforschung GmbH (ISFH)
  • Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU Erlangen-Nürnberg)
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Details

OriginalspracheEnglisch
Aufsatznummer123701
FachzeitschriftJournal of applied physics
Jahrgang102
Ausgabenummer12
PublikationsstatusVeröffentlicht - 17 Dez. 2007
Extern publiziertJa

Abstract

The recombination activity of interstitial chromium (Cri) and pairs of interstitial chromium and substitutional boron (Cri Bs) in crystalline silicon is studied by combining temperature- and injection-dependent lifetime and deep-level transient spectroscopy measurements on intentionally chromium-contaminated n - and p -type silicon wafers. Cri as well as Cri Bs pairs are found to be one order of magnitude less recombination active than widely assumed. In the case of Cri, a defect energy level of EC - Et =0.24 eV, an electron capture cross section of n =2× 10-14 cm2, and a hole capture cross section of p =4× 10-15 cm2 are determined. For Cri Bs pairs, measurements on boron-doped p -type silicon result in Et - EV =0.28 eV, n =5× 10-15 cm2, and p =1× 10-14 cm2. Theoretical calculations using the Shockley-Read-Hall theory show that it depends crucially on the doping concentration whether Cri or Cri Bs is the more active recombination center. Using a calibration function calculated from the defect parameters determined in this study, lifetime changes measured before and after thermal dissociation of Cri Bs pairs can be used to determine the interstitial chromium concentration in boron-doped silicon.

ASJC Scopus Sachgebiete

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Recombination activity of interstitial chromium and chromium-boron pairs in silicon. / Schmidt, Jan; Krain, Rafael; Bothe, Karsten et al.
in: Journal of applied physics, Jahrgang 102, Nr. 12, 123701, 17.12.2007.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Schmidt J, Krain R, Bothe K, Pensl G, Beljakowa S. Recombination activity of interstitial chromium and chromium-boron pairs in silicon. Journal of applied physics. 2007 Dez 17;102(12):123701. doi: 10.1063/1.2822452
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abstract = "The recombination activity of interstitial chromium (Cri) and pairs of interstitial chromium and substitutional boron (Cri Bs) in crystalline silicon is studied by combining temperature- and injection-dependent lifetime and deep-level transient spectroscopy measurements on intentionally chromium-contaminated n - and p -type silicon wafers. Cri as well as Cri Bs pairs are found to be one order of magnitude less recombination active than widely assumed. In the case of Cri, a defect energy level of EC - Et =0.24 eV, an electron capture cross section of n =2× 10-14 cm2, and a hole capture cross section of p =4× 10-15 cm2 are determined. For Cri Bs pairs, measurements on boron-doped p -type silicon result in Et - EV =0.28 eV, n =5× 10-15 cm2, and p =1× 10-14 cm2. Theoretical calculations using the Shockley-Read-Hall theory show that it depends crucially on the doping concentration whether Cri or Cri Bs is the more active recombination center. Using a calibration function calculated from the defect parameters determined in this study, lifetime changes measured before and after thermal dissociation of Cri Bs pairs can be used to determine the interstitial chromium concentration in boron-doped silicon.",
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AU - Schmidt, Jan

AU - Krain, Rafael

AU - Bothe, Karsten

AU - Pensl, Gerhard

AU - Beljakowa, Svetlana

PY - 2007/12/17

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