Reaction Behavior of Autoclaved Aerated Concrete and Sodium Aluminate at Mild Alkaline and Acid Hydrothermal Conditions: Model for AAC Recycling

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Andrea Hartmann
  • Josef C. Buhl

Organisationseinheiten

Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)441-450
Seitenumfang10
FachzeitschriftJournal of Materials in Civil Engineering
Jahrgang24
Ausgabenummer4
Frühes Online-Datum16 Sept. 2011
PublikationsstatusElektronisch veröffentlicht (E-Pub) - 16 Sept. 2011

Abstract

Recyclable fractions such as calcium and sodium aluminosilicates including zeolite sodalite (SOD) were obtained from hydrothermal treatment of autoclaved aerated concrete (AAC) waste material under addition of sodium aluminate. Three experimental series were performed using hydrothermal conditions at temperatures of 80°C and 180°C (autogeneous pressure) and AAC aluminate mass ratios of 0.8 and 2.0. Different solvents were applied in each series; whereas the reactions were carried out in water or 1-molar NaOH, a special two-step process was developed, starting with acid leaching of AAC (1-molar citric acid), followed by alkaline treatment of the whole slurry in 1-molar NaOH. Final products were analyzed by X-ray powder diffraction. Selected samples were further investigated by scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR). The results exhibit model character for new ways of resource recycling of AAC.

ASJC Scopus Sachgebiete

Ziele für nachhaltige Entwicklung

Zitieren

Reaction Behavior of Autoclaved Aerated Concrete and Sodium Aluminate at Mild Alkaline and Acid Hydrothermal Conditions: Model for AAC Recycling. / Hartmann, Andrea; Buhl, Josef C.
in: Journal of Materials in Civil Engineering, Jahrgang 24, Nr. 4, 16.09.2011, S. 441-450.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Download
@article{a090af851c594fbaaf911735a2c9fb19,
title = "Reaction Behavior of Autoclaved Aerated Concrete and Sodium Aluminate at Mild Alkaline and Acid Hydrothermal Conditions: Model for AAC Recycling",
abstract = "Recyclable fractions such as calcium and sodium aluminosilicates including zeolite sodalite (SOD) were obtained from hydrothermal treatment of autoclaved aerated concrete (AAC) waste material under addition of sodium aluminate. Three experimental series were performed using hydrothermal conditions at temperatures of 80°C and 180°C (autogeneous pressure) and AAC aluminate mass ratios of 0.8 and 2.0. Different solvents were applied in each series; whereas the reactions were carried out in water or 1-molar NaOH, a special two-step process was developed, starting with acid leaching of AAC (1-molar citric acid), followed by alkaline treatment of the whole slurry in 1-molar NaOH. Final products were analyzed by X-ray powder diffraction. Selected samples were further investigated by scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR). The results exhibit model character for new ways of resource recycling of AAC.",
keywords = "Aluminosilicates, Autoclaved aerated concrete, Building materials recycling, FTIR, Hydrothermal synthesis, SEM/EDX, XRD, Zeolites",
author = "Andrea Hartmann and Buhl, {Josef C.}",
year = "2011",
month = sep,
day = "16",
doi = "10.1061/(ASCE)MT.1943-5533.0000392",
language = "English",
volume = "24",
pages = "441--450",
journal = "Journal of Materials in Civil Engineering",
issn = "0899-1561",
publisher = "American Society of Civil Engineers (ASCE)",
number = "4",

}

Download

TY - JOUR

T1 - Reaction Behavior of Autoclaved Aerated Concrete and Sodium Aluminate at Mild Alkaline and Acid Hydrothermal Conditions

T2 - Model for AAC Recycling

AU - Hartmann, Andrea

AU - Buhl, Josef C.

PY - 2011/9/16

Y1 - 2011/9/16

N2 - Recyclable fractions such as calcium and sodium aluminosilicates including zeolite sodalite (SOD) were obtained from hydrothermal treatment of autoclaved aerated concrete (AAC) waste material under addition of sodium aluminate. Three experimental series were performed using hydrothermal conditions at temperatures of 80°C and 180°C (autogeneous pressure) and AAC aluminate mass ratios of 0.8 and 2.0. Different solvents were applied in each series; whereas the reactions were carried out in water or 1-molar NaOH, a special two-step process was developed, starting with acid leaching of AAC (1-molar citric acid), followed by alkaline treatment of the whole slurry in 1-molar NaOH. Final products were analyzed by X-ray powder diffraction. Selected samples were further investigated by scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR). The results exhibit model character for new ways of resource recycling of AAC.

AB - Recyclable fractions such as calcium and sodium aluminosilicates including zeolite sodalite (SOD) were obtained from hydrothermal treatment of autoclaved aerated concrete (AAC) waste material under addition of sodium aluminate. Three experimental series were performed using hydrothermal conditions at temperatures of 80°C and 180°C (autogeneous pressure) and AAC aluminate mass ratios of 0.8 and 2.0. Different solvents were applied in each series; whereas the reactions were carried out in water or 1-molar NaOH, a special two-step process was developed, starting with acid leaching of AAC (1-molar citric acid), followed by alkaline treatment of the whole slurry in 1-molar NaOH. Final products were analyzed by X-ray powder diffraction. Selected samples were further investigated by scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR). The results exhibit model character for new ways of resource recycling of AAC.

KW - Aluminosilicates

KW - Autoclaved aerated concrete

KW - Building materials recycling

KW - FTIR

KW - Hydrothermal synthesis

KW - SEM/EDX

KW - XRD

KW - Zeolites

UR - http://www.scopus.com/inward/record.url?scp=84860356486&partnerID=8YFLogxK

U2 - 10.1061/(ASCE)MT.1943-5533.0000392

DO - 10.1061/(ASCE)MT.1943-5533.0000392

M3 - Article

AN - SCOPUS:84860356486

VL - 24

SP - 441

EP - 450

JO - Journal of Materials in Civil Engineering

JF - Journal of Materials in Civil Engineering

SN - 0899-1561

IS - 4

ER -