Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 21063-21069 |
| Seitenumfang | 7 |
| Fachzeitschrift | Physical Chemistry Chemical Physics |
| Jahrgang | 13 |
| Ausgabenummer | 47 |
| Publikationsstatus | Veröffentlicht - 21 Dez. 2011 |
Abstract
Nicotine has been investigated in the gas phase and two conformational forms were characterized through their rotational spectra. Two spectroscopic techniques have been used to obtain the spectra: a new design of broadband Fourier transform microwave (FTMW) spectroscopy with an in-phase/quadrature- phase-modulation passage-acquired-coherence technique (IMPACT) and narrowband FTMW spectroscopy with coaxially oriented beam-resonator arrangement (COBRA). The rotational, centrifugal distortion and hyperfine quadrupole coupling constants of two conformers of nicotine have been determined and found to be in N-methyl trans configurations with the pyridine and pyrrolidine rings perpendicular to one another. The quadrupole hyperfine structure originated by two 14N nuclei has been completely resolved for both conformers and used for their unambiguous identification.
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in: Physical Chemistry Chemical Physics, Jahrgang 13, Nr. 47, 21.12.2011, S. 21063-21069.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Rapid probe of the nicotine spectra by high-resolution rotational spectroscopy
AU - Grabow, Jens Uwe
AU - Mata, S.
AU - Alonso, José L.
AU - Peña, I.
AU - Blanco, S.
AU - López, Juan C.
AU - Cabezas, C.
PY - 2011/12/21
Y1 - 2011/12/21
N2 - Nicotine has been investigated in the gas phase and two conformational forms were characterized through their rotational spectra. Two spectroscopic techniques have been used to obtain the spectra: a new design of broadband Fourier transform microwave (FTMW) spectroscopy with an in-phase/quadrature- phase-modulation passage-acquired-coherence technique (IMPACT) and narrowband FTMW spectroscopy with coaxially oriented beam-resonator arrangement (COBRA). The rotational, centrifugal distortion and hyperfine quadrupole coupling constants of two conformers of nicotine have been determined and found to be in N-methyl trans configurations with the pyridine and pyrrolidine rings perpendicular to one another. The quadrupole hyperfine structure originated by two 14N nuclei has been completely resolved for both conformers and used for their unambiguous identification.
AB - Nicotine has been investigated in the gas phase and two conformational forms were characterized through their rotational spectra. Two spectroscopic techniques have been used to obtain the spectra: a new design of broadband Fourier transform microwave (FTMW) spectroscopy with an in-phase/quadrature- phase-modulation passage-acquired-coherence technique (IMPACT) and narrowband FTMW spectroscopy with coaxially oriented beam-resonator arrangement (COBRA). The rotational, centrifugal distortion and hyperfine quadrupole coupling constants of two conformers of nicotine have been determined and found to be in N-methyl trans configurations with the pyridine and pyrrolidine rings perpendicular to one another. The quadrupole hyperfine structure originated by two 14N nuclei has been completely resolved for both conformers and used for their unambiguous identification.
UR - http://www.scopus.com/inward/record.url?scp=82355192026&partnerID=8YFLogxK
U2 - 10.1039/c1cp22197c
DO - 10.1039/c1cp22197c
M3 - Article
C2 - 22020263
AN - SCOPUS:82355192026
VL - 13
SP - 21063
EP - 21069
JO - Physical Chemistry Chemical Physics
JF - Physical Chemistry Chemical Physics
SN - 1463-9076
IS - 47
ER -