Pulsed electron source for atmospheric pressure chemical ionization in ion mobility spectrometry

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OriginalspracheEnglisch
Titel des Sammelwerks2017 30th International Vacuum Nanoelectronics Conference (IVNC)
Herausgeber/-innenChristoph Langer, Robert Lawrowski
Herausgeber (Verlag)Institute of Electrical and Electronics Engineers Inc.
Seiten102-103
Seitenumfang2
ISBN (elektronisch)9781509039753, 978-1-5090-3974-6
ISBN (Print)978-1-5090-3976-0
PublikationsstatusVeröffentlicht - 2017
Veranstaltung30th International Vacuum Nanoelectronics Conference - Regensburg, Deutschland
Dauer: 10 Juli 201714 Juli 2017
Konferenznummer: 30
https://www.aconf.org/conf_92671.html

Publikationsreihe

NameInternational Vacuum Nanoelectronics Conference
Herausgeber (Verlag)IEEE
ISSN (elektronisch)2380-6311

Abstract

Ion mobility spectrometers (IMS) are measurement devices for fast and ultra-sensitive trace gas analysis. Most IMS employ radioactive electron sources, such as 3H or 63Ni, to provide free electrons with high kinetic energy at atmospheric pressure for initiating a chemical gas phase ionization of the analytes. The disadvantage of these radioactive materials are legal restrictions and the electron emission cannot be adjusted or turned off. Therefore, we developed a non-radioactive electron source and replaced the 3H-source of our existing IMS, leading to comparable spectra. An advantage of our non-radioactive electron source is that it can operate in a fast pulsed mode. By optimizing the geometric parameters and developing fast control electronics, we can achieve short electron emission pulses with high intensities and adjustable pulse width down to a few nanoseconds. This allows to control the ionization process, which can enhance the analytical performance of the IMS. Furthermore, a miniaturized non-radioactive electron source is desirable, e.g. for hand-held IMS devices. Therefore, we developed an emission current control for field emitter cathodes and investigated their suitability for this application.

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Pulsed electron source for atmospheric pressure chemical ionization in ion mobility spectrometry. / Bunert, Erik; Heptner, Andre; Kirk, Ansgar T. et al.
2017 30th International Vacuum Nanoelectronics Conference (IVNC). Hrsg. / Christoph Langer; Robert Lawrowski. Institute of Electrical and Electronics Engineers Inc., 2017. S. 102-103 8051563 (International Vacuum Nanoelectronics Conference).

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Bunert, E, Heptner, A, Kirk, AT, Käbein, O, Zimmermann, S, Kusch, A & Wurz, MC 2017, Pulsed electron source for atmospheric pressure chemical ionization in ion mobility spectrometry. in C Langer & R Lawrowski (Hrsg.), 2017 30th International Vacuum Nanoelectronics Conference (IVNC)., 8051563, International Vacuum Nanoelectronics Conference, Institute of Electrical and Electronics Engineers Inc., S. 102-103, 30th International Vacuum Nanoelectronics Conference, Regensburg, Baden-Württemberg, Deutschland, 10 Juli 2017. https://doi.org/10.1109/IVNC.2017.8051563, https://doi.org/10.15488/4417
Bunert, E., Heptner, A., Kirk, A. T., Käbein, O., Zimmermann, S., Kusch, A., & Wurz, M. C. (2017). Pulsed electron source for atmospheric pressure chemical ionization in ion mobility spectrometry. In C. Langer, & R. Lawrowski (Hrsg.), 2017 30th International Vacuum Nanoelectronics Conference (IVNC) (S. 102-103). Artikel 8051563 (International Vacuum Nanoelectronics Conference). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/IVNC.2017.8051563, https://doi.org/10.15488/4417
Bunert E, Heptner A, Kirk AT, Käbein O, Zimmermann S, Kusch A et al. Pulsed electron source for atmospheric pressure chemical ionization in ion mobility spectrometry. in Langer C, Lawrowski R, Hrsg., 2017 30th International Vacuum Nanoelectronics Conference (IVNC). Institute of Electrical and Electronics Engineers Inc. 2017. S. 102-103. 8051563. (International Vacuum Nanoelectronics Conference). doi: 10.1109/IVNC.2017.8051563, 10.15488/4417
Bunert, Erik ; Heptner, Andre ; Kirk, Ansgar T. et al. / Pulsed electron source for atmospheric pressure chemical ionization in ion mobility spectrometry. 2017 30th International Vacuum Nanoelectronics Conference (IVNC). Hrsg. / Christoph Langer ; Robert Lawrowski. Institute of Electrical and Electronics Engineers Inc., 2017. S. 102-103 (International Vacuum Nanoelectronics Conference).
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abstract = "Ion mobility spectrometers (IMS) are measurement devices for fast and ultra-sensitive trace gas analysis. Most IMS employ radioactive electron sources, such as 3H or 63Ni, to provide free electrons with high kinetic energy at atmospheric pressure for initiating a chemical gas phase ionization of the analytes. The disadvantage of these radioactive materials are legal restrictions and the electron emission cannot be adjusted or turned off. Therefore, we developed a non-radioactive electron source and replaced the 3H-source of our existing IMS, leading to comparable spectra. An advantage of our non-radioactive electron source is that it can operate in a fast pulsed mode. By optimizing the geometric parameters and developing fast control electronics, we can achieve short electron emission pulses with high intensities and adjustable pulse width down to a few nanoseconds. This allows to control the ionization process, which can enhance the analytical performance of the IMS. Furthermore, a miniaturized non-radioactive electron source is desirable, e.g. for hand-held IMS devices. Therefore, we developed an emission current control for field emitter cathodes and investigated their suitability for this application.",
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TY - GEN

T1 - Pulsed electron source for atmospheric pressure chemical ionization in ion mobility spectrometry

AU - Bunert, Erik

AU - Heptner, Andre

AU - Kirk, Ansgar T.

AU - Käbein, Oliver

AU - Zimmermann, Stefan

AU - Kusch, Alexander

AU - Wurz, Marc Christopher

N1 - Conference code: 30

PY - 2017

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N2 - Ion mobility spectrometers (IMS) are measurement devices for fast and ultra-sensitive trace gas analysis. Most IMS employ radioactive electron sources, such as 3H or 63Ni, to provide free electrons with high kinetic energy at atmospheric pressure for initiating a chemical gas phase ionization of the analytes. The disadvantage of these radioactive materials are legal restrictions and the electron emission cannot be adjusted or turned off. Therefore, we developed a non-radioactive electron source and replaced the 3H-source of our existing IMS, leading to comparable spectra. An advantage of our non-radioactive electron source is that it can operate in a fast pulsed mode. By optimizing the geometric parameters and developing fast control electronics, we can achieve short electron emission pulses with high intensities and adjustable pulse width down to a few nanoseconds. This allows to control the ionization process, which can enhance the analytical performance of the IMS. Furthermore, a miniaturized non-radioactive electron source is desirable, e.g. for hand-held IMS devices. Therefore, we developed an emission current control for field emitter cathodes and investigated their suitability for this application.

AB - Ion mobility spectrometers (IMS) are measurement devices for fast and ultra-sensitive trace gas analysis. Most IMS employ radioactive electron sources, such as 3H or 63Ni, to provide free electrons with high kinetic energy at atmospheric pressure for initiating a chemical gas phase ionization of the analytes. The disadvantage of these radioactive materials are legal restrictions and the electron emission cannot be adjusted or turned off. Therefore, we developed a non-radioactive electron source and replaced the 3H-source of our existing IMS, leading to comparable spectra. An advantage of our non-radioactive electron source is that it can operate in a fast pulsed mode. By optimizing the geometric parameters and developing fast control electronics, we can achieve short electron emission pulses with high intensities and adjustable pulse width down to a few nanoseconds. This allows to control the ionization process, which can enhance the analytical performance of the IMS. Furthermore, a miniaturized non-radioactive electron source is desirable, e.g. for hand-held IMS devices. Therefore, we developed an emission current control for field emitter cathodes and investigated their suitability for this application.

KW - APCI

KW - emission current control

KW - field emission

KW - ion mobility spectrometry

KW - non-radioacitve electron source

KW - pulsed electron emission

KW - thermionic emission

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DO - 10.1109/IVNC.2017.8051563

M3 - Conference contribution

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BT - 2017 30th International Vacuum Nanoelectronics Conference (IVNC)

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ER -

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