Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • H. K. Tchakouté
  • D. E. Tchinda Mabah
  • C. Henning Rüscher
  • E. Kamseu
  • F. Andreola
  • M. C. Bignozzi
  • C. Leonelli

Organisationseinheiten

Externe Organisationen

  • University of Yaounde I
  • University of Modena and Reggio Emilia
  • Università di Bologna
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Details

OriginalspracheEnglisch
Seiten (von - bis)149-161
Seitenumfang13
FachzeitschriftJournal of Asian Ceramic Societies
Jahrgang8
Ausgabenummer1
PublikationsstatusVeröffentlicht - 28 Jan. 2020

Abstract

This work aims to prepare low-cost nanocomposite and microcomposite with lower molar ratio CaO/SiO2 (0.4). Nano-silica, rice husk ash and calcined chicken eggshell have been used as silica and calcium sources. Metakaolin has been separately replaced by 0, 10 and 20 wt% of each composite in order to study their behavior on the properties of geopolymers. The hardener used is sodium waterglass from rice husk ash. The surface area of nano-silica and rice husk ash was 54.40 and 4.08 m2/g, respectively. The cumulative volumes of the control geopolymer, the ones containing 10 wt% of microcomposite and nanocomposite are 119.71, 89.92 and 110.49 mm3/g, respectively. The compressive strength of the control specimen is around 64.02 MPa. The one using 10 wt% of microcomposite was 68.97 MPa. It drops to 42.88 MPa when metakaolin was replaced by 20 wt % of microcomposite. Whereas the one using 10 wt% of nanocomposite was 30.03 MPa and it decreases to 26.05 MPa when metakaolin was substituted by 20 wt% of nanocomposite. It can be concluded that 10 wt% of microcomposite could be mixed to metakaolin for strength development and nanocomposite does not recommend to use as an additive for producing high strength of geopolymer cements.

ASJC Scopus Sachgebiete

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Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements. / Tchakouté, H. K.; Tchinda Mabah, D. E.; Henning Rüscher, C. et al.
in: Journal of Asian Ceramic Societies, Jahrgang 8, Nr. 1, 28.01.2020, S. 149-161.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Tchakouté, HK, Tchinda Mabah, DE, Henning Rüscher, C, Kamseu, E, Andreola, F, Bignozzi, MC & Leonelli, C 2020, 'Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements', Journal of Asian Ceramic Societies, Jg. 8, Nr. 1, S. 149-161. https://doi.org/10.1080/21870764.2020.1718860, https://doi.org/10.15488/10710
Tchakouté, H. K., Tchinda Mabah, D. E., Henning Rüscher, C., Kamseu, E., Andreola, F., Bignozzi, M. C., & Leonelli, C. (2020). Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements. Journal of Asian Ceramic Societies, 8(1), 149-161. https://doi.org/10.1080/21870764.2020.1718860, https://doi.org/10.15488/10710
Tchakouté HK, Tchinda Mabah DE, Henning Rüscher C, Kamseu E, Andreola F, Bignozzi MC et al. Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements. Journal of Asian Ceramic Societies. 2020 Jan 28;8(1):149-161. doi: 10.1080/21870764.2020.1718860, 10.15488/10710
Tchakouté, H. K. ; Tchinda Mabah, D. E. ; Henning Rüscher, C. et al. / Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements. in: Journal of Asian Ceramic Societies. 2020 ; Jahrgang 8, Nr. 1. S. 149-161.
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title = "Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements",
abstract = "This work aims to prepare low-cost nanocomposite and microcomposite with lower molar ratio CaO/SiO2 (0.4). Nano-silica, rice husk ash and calcined chicken eggshell have been used as silica and calcium sources. Metakaolin has been separately replaced by 0, 10 and 20 wt% of each composite in order to study their behavior on the properties of geopolymers. The hardener used is sodium waterglass from rice husk ash. The surface area of nano-silica and rice husk ash was 54.40 and 4.08 m2/g, respectively. The cumulative volumes of the control geopolymer, the ones containing 10 wt% of microcomposite and nanocomposite are 119.71, 89.92 and 110.49 mm3/g, respectively. The compressive strength of the control specimen is around 64.02 MPa. The one using 10 wt% of microcomposite was 68.97 MPa. It drops to 42.88 MPa when metakaolin was replaced by 20 wt % of microcomposite. Whereas the one using 10 wt% of nanocomposite was 30.03 MPa and it decreases to 26.05 MPa when metakaolin was substituted by 20 wt% of nanocomposite. It can be concluded that 10 wt% of microcomposite could be mixed to metakaolin for strength development and nanocomposite does not recommend to use as an additive for producing high strength of geopolymer cements.",
keywords = "geopolymer cements, Metakaolin, microcomposite, nanocomposite, sodium waterglass",
author = "Tchakout{\'e}, {H. K.} and {Tchinda Mabah}, {D. E.} and {Henning R{\"u}scher}, C. and E. Kamseu and F. Andreola and Bignozzi, {M. C.} and C. Leonelli",
note = "Funding Information: Dr. Herv{\'e} Tchakout{\'e} Kouamo gratefully acknowledges the Alexander von Humboldt Foundation for financial support this work under the grant N° KAM/1155741 GFHERMES-P. The authors would like to thank Dr. Valerie Petrov for SEM observations. ",
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day = "28",
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TY - JOUR

T1 - Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements

AU - Tchakouté, H. K.

AU - Tchinda Mabah, D. E.

AU - Henning Rüscher, C.

AU - Kamseu, E.

AU - Andreola, F.

AU - Bignozzi, M. C.

AU - Leonelli, C.

N1 - Funding Information: Dr. Hervé Tchakouté Kouamo gratefully acknowledges the Alexander von Humboldt Foundation for financial support this work under the grant N° KAM/1155741 GFHERMES-P. The authors would like to thank Dr. Valerie Petrov for SEM observations.

PY - 2020/1/28

Y1 - 2020/1/28

N2 - This work aims to prepare low-cost nanocomposite and microcomposite with lower molar ratio CaO/SiO2 (0.4). Nano-silica, rice husk ash and calcined chicken eggshell have been used as silica and calcium sources. Metakaolin has been separately replaced by 0, 10 and 20 wt% of each composite in order to study their behavior on the properties of geopolymers. The hardener used is sodium waterglass from rice husk ash. The surface area of nano-silica and rice husk ash was 54.40 and 4.08 m2/g, respectively. The cumulative volumes of the control geopolymer, the ones containing 10 wt% of microcomposite and nanocomposite are 119.71, 89.92 and 110.49 mm3/g, respectively. The compressive strength of the control specimen is around 64.02 MPa. The one using 10 wt% of microcomposite was 68.97 MPa. It drops to 42.88 MPa when metakaolin was replaced by 20 wt % of microcomposite. Whereas the one using 10 wt% of nanocomposite was 30.03 MPa and it decreases to 26.05 MPa when metakaolin was substituted by 20 wt% of nanocomposite. It can be concluded that 10 wt% of microcomposite could be mixed to metakaolin for strength development and nanocomposite does not recommend to use as an additive for producing high strength of geopolymer cements.

AB - This work aims to prepare low-cost nanocomposite and microcomposite with lower molar ratio CaO/SiO2 (0.4). Nano-silica, rice husk ash and calcined chicken eggshell have been used as silica and calcium sources. Metakaolin has been separately replaced by 0, 10 and 20 wt% of each composite in order to study their behavior on the properties of geopolymers. The hardener used is sodium waterglass from rice husk ash. The surface area of nano-silica and rice husk ash was 54.40 and 4.08 m2/g, respectively. The cumulative volumes of the control geopolymer, the ones containing 10 wt% of microcomposite and nanocomposite are 119.71, 89.92 and 110.49 mm3/g, respectively. The compressive strength of the control specimen is around 64.02 MPa. The one using 10 wt% of microcomposite was 68.97 MPa. It drops to 42.88 MPa when metakaolin was replaced by 20 wt % of microcomposite. Whereas the one using 10 wt% of nanocomposite was 30.03 MPa and it decreases to 26.05 MPa when metakaolin was substituted by 20 wt% of nanocomposite. It can be concluded that 10 wt% of microcomposite could be mixed to metakaolin for strength development and nanocomposite does not recommend to use as an additive for producing high strength of geopolymer cements.

KW - geopolymer cements

KW - Metakaolin

KW - microcomposite

KW - nanocomposite

KW - sodium waterglass

UR - http://www.scopus.com/inward/record.url?scp=85078433871&partnerID=8YFLogxK

U2 - 10.1080/21870764.2020.1718860

DO - 10.1080/21870764.2020.1718860

M3 - Article

AN - SCOPUS:85078433871

VL - 8

SP - 149

EP - 161

JO - Journal of Asian Ceramic Societies

JF - Journal of Asian Ceramic Societies

IS - 1

ER -