Pore accessibility and connectivity of mineral and kerogen phases in shales

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Autoren

  • Qinhong Hu
  • Xubo Gao
  • Zhiye Gao
  • Robert Ewing
  • Stefan Dultz
  • Josef Kaufmann

Externe Organisationen

  • University of Texas at Arlington
  • China University of Geosciences (CUG)
  • University of Texas at Austin
  • China Univeristy of Petroleum - Beijing
  • Iowa State University
  • Eidgenössische Materialprüfungs- und Forschungsanstalt (EMPA)
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Titel des SammelwerksSociety of Petroleum Engineers - SPE/AAPG/SEG Unconventional Resources Technology Conference
Herausgeber (Verlag)Society of Petroleum Engineers (SPE)
ISBN (elektronisch)9781613993606
PublikationsstatusVeröffentlicht - 2016
VeranstaltungSPE/AAPG/SEG Unconventional Resources Technology Conference - Denver, USA / Vereinigte Staaten
Dauer: 25 Aug. 201427 Aug. 2014

Abstract

The main barrier to sustainable development of US shale, the pore structure of the nanopores storing and transporting hydrocarbon, has been quietly ignored. Fluid flow and mass transport in porous media is controlled by pore structure, which has both geometric and topological characteristics; these characteristics therefore affect exploration and production of hydrocarbons. Considering the composition of mineral and kerogen phases and their associated nanopores in shales, we have studied tracer penetration and distribution, and its association with mineral and organic kerogen phases. We examined imbibition behavior, and imbibed tracer distribution, for fluids (API brine or n-decane) imbibed into initially dry Barnett shale samples. Pore connection was also probed by injecting molten Wood's metal alloy at pressures as high as 6,000 bars, followed by imaging and elemental mapping. The extremely sensitive detection of Wood's metal component elements by laser ablation-ICP-MS mapping reveals that only about 1/1000th of the edge-accessible porosity is connected in the sample interior, which is consistent with other experimental approaches and theoretical interpretation of pore connectivity based on percolation theory. This sparse pore space connection within the shale matrix limits fracture-matrix exchange in fractured shale, resulting in steep initial production decline and overall low recovery.

ASJC Scopus Sachgebiete

Ziele für nachhaltige Entwicklung

Zitieren

Pore accessibility and connectivity of mineral and kerogen phases in shales. / Hu, Qinhong; Gao, Xubo; Gao, Zhiye et al.
Society of Petroleum Engineers - SPE/AAPG/SEG Unconventional Resources Technology Conference. Society of Petroleum Engineers (SPE), 2016.

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Hu, Q, Gao, X, Gao, Z, Ewing, R, Dultz, S & Kaufmann, J 2016, Pore accessibility and connectivity of mineral and kerogen phases in shales. in Society of Petroleum Engineers - SPE/AAPG/SEG Unconventional Resources Technology Conference. Society of Petroleum Engineers (SPE), SPE/AAPG/SEG Unconventional Resources Technology Conference, Denver, USA / Vereinigte Staaten, 25 Aug. 2014. https://doi.org/10.15530/urtec-2014-1922943
Hu, Q., Gao, X., Gao, Z., Ewing, R., Dultz, S., & Kaufmann, J. (2016). Pore accessibility and connectivity of mineral and kerogen phases in shales. In Society of Petroleum Engineers - SPE/AAPG/SEG Unconventional Resources Technology Conference Society of Petroleum Engineers (SPE). https://doi.org/10.15530/urtec-2014-1922943
Hu Q, Gao X, Gao Z, Ewing R, Dultz S, Kaufmann J. Pore accessibility and connectivity of mineral and kerogen phases in shales. in Society of Petroleum Engineers - SPE/AAPG/SEG Unconventional Resources Technology Conference. Society of Petroleum Engineers (SPE). 2016 doi: 10.15530/urtec-2014-1922943
Hu, Qinhong ; Gao, Xubo ; Gao, Zhiye et al. / Pore accessibility and connectivity of mineral and kerogen phases in shales. Society of Petroleum Engineers - SPE/AAPG/SEG Unconventional Resources Technology Conference. Society of Petroleum Engineers (SPE), 2016.
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abstract = "The main barrier to sustainable development of US shale, the pore structure of the nanopores storing and transporting hydrocarbon, has been quietly ignored. Fluid flow and mass transport in porous media is controlled by pore structure, which has both geometric and topological characteristics; these characteristics therefore affect exploration and production of hydrocarbons. Considering the composition of mineral and kerogen phases and their associated nanopores in shales, we have studied tracer penetration and distribution, and its association with mineral and organic kerogen phases. We examined imbibition behavior, and imbibed tracer distribution, for fluids (API brine or n-decane) imbibed into initially dry Barnett shale samples. Pore connection was also probed by injecting molten Wood's metal alloy at pressures as high as 6,000 bars, followed by imaging and elemental mapping. The extremely sensitive detection of Wood's metal component elements by laser ablation-ICP-MS mapping reveals that only about 1/1000th of the edge-accessible porosity is connected in the sample interior, which is consistent with other experimental approaches and theoretical interpretation of pore connectivity based on percolation theory. This sparse pore space connection within the shale matrix limits fracture-matrix exchange in fractured shale, resulting in steep initial production decline and overall low recovery.",
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AU - Hu, Qinhong

AU - Gao, Xubo

AU - Gao, Zhiye

AU - Ewing, Robert

AU - Dultz, Stefan

AU - Kaufmann, Josef

PY - 2016

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AB - The main barrier to sustainable development of US shale, the pore structure of the nanopores storing and transporting hydrocarbon, has been quietly ignored. Fluid flow and mass transport in porous media is controlled by pore structure, which has both geometric and topological characteristics; these characteristics therefore affect exploration and production of hydrocarbons. Considering the composition of mineral and kerogen phases and their associated nanopores in shales, we have studied tracer penetration and distribution, and its association with mineral and organic kerogen phases. We examined imbibition behavior, and imbibed tracer distribution, for fluids (API brine or n-decane) imbibed into initially dry Barnett shale samples. Pore connection was also probed by injecting molten Wood's metal alloy at pressures as high as 6,000 bars, followed by imaging and elemental mapping. The extremely sensitive detection of Wood's metal component elements by laser ablation-ICP-MS mapping reveals that only about 1/1000th of the edge-accessible porosity is connected in the sample interior, which is consistent with other experimental approaches and theoretical interpretation of pore connectivity based on percolation theory. This sparse pore space connection within the shale matrix limits fracture-matrix exchange in fractured shale, resulting in steep initial production decline and overall low recovery.

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