Polycyclic Aromatic Hydrocarbons (PAH) in Different Forest Humus Types

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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  • Technische Universität München (TUM)
  • Universität Bayreuth
  • Infutec Dr. Neumayr GmbH Institut für Umwelttechnik
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Details

OriginalspracheEnglisch
Seiten (von - bis)24-31
Seitenumfang8
FachzeitschriftEnvironmental Science and Pollution Research
Jahrgang3
Ausgabenummer1
PublikationsstatusVeröffentlicht - März 1996
Extern publiziertJa

Abstract

The behavior of 20 PAH in the organic layers of a L mull, an Of mull and a mor was assessed by a combined approach of a soil profile study, and the analysis of particle-size separates. Increasing PAH concentrations with depth in the mor profile (L, 866 μg kg-1; Of, 2902 μg kg-1; Oh, 10489 pg kg-1) were assigned to selective enrichment during organic matter decomposition. PAH were further highly enriched within the finer separates. For the L horizons, significant positive correlations were established between the enrichment of individual PAH (as observed from the decomposition gradient between the >2-mm fraction and the <0.05-mm fraction), and the KOW, for each compound. The slope of the regression line, m, described the degree of differentiation between low- and high-molecular PAH during litter decomposition. Since m was greatest in the most biologically active humus type (L mull, 0.33) and smallest in the most inactive (mor, 0.20), microbial breakdown was assumed as the dominating process for this differentiation. The results also indicated that decomposition processes had already taken place in the L horizons, leading to morphological and chemical changes of organic matter, and to an enrichment of high molecular PAH.

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Polycyclic Aromatic Hydrocarbons (PAH) in Different Forest Humus Types. / Pichler, Martin; Guggenberger, Georg; Hartmann, Robert et al.
in: Environmental Science and Pollution Research, Jahrgang 3, Nr. 1, 03.1996, S. 24-31.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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abstract = "The behavior of 20 PAH in the organic layers of a L mull, an Of mull and a mor was assessed by a combined approach of a soil profile study, and the analysis of particle-size separates. Increasing PAH concentrations with depth in the mor profile (L, 866 μg kg-1; Of, 2902 μg kg-1; Oh, 10489 pg kg-1) were assigned to selective enrichment during organic matter decomposition. PAH were further highly enriched within the finer separates. For the L horizons, significant positive correlations were established between the enrichment of individual PAH (as observed from the decomposition gradient between the >2-mm fraction and the <0.05-mm fraction), and the KOW, for each compound. The slope of the regression line, m, described the degree of differentiation between low- and high-molecular PAH during litter decomposition. Since m was greatest in the most biologically active humus type (L mull, 0.33) and smallest in the most inactive (mor, 0.20), microbial breakdown was assumed as the dominating process for this differentiation. The results also indicated that decomposition processes had already taken place in the L horizons, leading to morphological and chemical changes of organic matter, and to an enrichment of high molecular PAH.",
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AU - Pichler, Martin

AU - Guggenberger, Georg

AU - Hartmann, Robert

AU - Zech, Wolfgang

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N2 - The behavior of 20 PAH in the organic layers of a L mull, an Of mull and a mor was assessed by a combined approach of a soil profile study, and the analysis of particle-size separates. Increasing PAH concentrations with depth in the mor profile (L, 866 μg kg-1; Of, 2902 μg kg-1; Oh, 10489 pg kg-1) were assigned to selective enrichment during organic matter decomposition. PAH were further highly enriched within the finer separates. For the L horizons, significant positive correlations were established between the enrichment of individual PAH (as observed from the decomposition gradient between the >2-mm fraction and the <0.05-mm fraction), and the KOW, for each compound. The slope of the regression line, m, described the degree of differentiation between low- and high-molecular PAH during litter decomposition. Since m was greatest in the most biologically active humus type (L mull, 0.33) and smallest in the most inactive (mor, 0.20), microbial breakdown was assumed as the dominating process for this differentiation. The results also indicated that decomposition processes had already taken place in the L horizons, leading to morphological and chemical changes of organic matter, and to an enrichment of high molecular PAH.

AB - The behavior of 20 PAH in the organic layers of a L mull, an Of mull and a mor was assessed by a combined approach of a soil profile study, and the analysis of particle-size separates. Increasing PAH concentrations with depth in the mor profile (L, 866 μg kg-1; Of, 2902 μg kg-1; Oh, 10489 pg kg-1) were assigned to selective enrichment during organic matter decomposition. PAH were further highly enriched within the finer separates. For the L horizons, significant positive correlations were established between the enrichment of individual PAH (as observed from the decomposition gradient between the >2-mm fraction and the <0.05-mm fraction), and the KOW, for each compound. The slope of the regression line, m, described the degree of differentiation between low- and high-molecular PAH during litter decomposition. Since m was greatest in the most biologically active humus type (L mull, 0.33) and smallest in the most inactive (mor, 0.20), microbial breakdown was assumed as the dominating process for this differentiation. The results also indicated that decomposition processes had already taken place in the L horizons, leading to morphological and chemical changes of organic matter, and to an enrichment of high molecular PAH.

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KW - Microbial decomposition

KW - Organic layers

KW - PAH differentiation

KW - PAH enrichment

KW - Particle size separates

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