Photomineralization of recalcitrant wastewaters by a novel magnetically recyclable boron doped-TiO2-SiO2 cobalt ferrite nanocomposite as a visible-driven heterogeneous photocatalyst

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autoren

  • H. Zangeneh
  • A.A. Zinatizadeh
  • M. Feyzi
  • S. Zinadini
  • D.W. Bahnemann

Organisationseinheiten

Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)6370-6381
Seitenumfang12
FachzeitschriftJournal of Environmental Chemical Engineering
Jahrgang6
Ausgabenummer5
Frühes Online-Datum2 Okt. 2018
PublikationsstatusVeröffentlicht - Okt. 2018

Abstract

In this work, different recalcitrant organic compounds including biologically treated palm oil mill effluent (POME), diazinon and paraquat dichloride and natural dye from algal growth in Solaymanshah's dam was degraded using a novel highly efficient magnetically visible driven photocatalyst (boron doped TiO 2-SiO 2 cobalt ferrite) which was synthesized by a sol gel hydrothermal method. The prepared nanocomposites were characterized by UV-vis diffuse reflectance (DRS) spectroscopy, X-ray diffraction (XRD), photoluminescence (PL), Fourier transform infrared (FT-IR), field emission scanning electron microscopy (FESEM) and vibrating sample magnetometer (VSM) analyses. The results revealed that boron doped-TiO 2-SiO 2 cobalt ferrite nanocomposite not only expanded the response region to the visible light but also reduced recombination of the photoinduced e -/h + pairs. The effects of various parameters, such as COD concentrations (300-800 mg/l), photocatalyst concentration (1.5-3.5 g/l) and pH (3-11) on the photocatalytic process were also evaluated. The COD contents was completely removed for the biologically treated POME, paraquat dichloride, diazinon, natural dye from algal growth in Solaymanshah dam's after 4/5, 3/5, 3 and 2/5 h, respectively at optimum conditions (initial COD concentration of 300 mg/l, catalyst loading 2/5 g/l and pH of 3). Furthermore, the magnetic nanocomposite can be easily recovered and separated with an extra magnet with a small loss of 0.01-0.05 g/l corresponding to 0.4-2 %. After being reused for three times, the reduction of COD removal efficiency of the natural dyes, diazinon, paraquat dichloride and biologically treated POME was about 1, 1, 3 and 4%, respectively that confirmed the photocatalytic stability of nanocomposite.

ASJC Scopus Sachgebiete

Zitieren

Photomineralization of recalcitrant wastewaters by a novel magnetically recyclable boron doped-TiO2-SiO2 cobalt ferrite nanocomposite as a visible-driven heterogeneous photocatalyst. / Zangeneh, H.; Zinatizadeh, A.A.; Feyzi, M. et al.
in: Journal of Environmental Chemical Engineering, Jahrgang 6, Nr. 5, 10.2018, S. 6370-6381.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Zangeneh, H, Zinatizadeh, AA, Feyzi, M, Zinadini, S & Bahnemann, DW 2018, 'Photomineralization of recalcitrant wastewaters by a novel magnetically recyclable boron doped-TiO2-SiO2 cobalt ferrite nanocomposite as a visible-driven heterogeneous photocatalyst', Journal of Environmental Chemical Engineering, Jg. 6, Nr. 5, S. 6370-6381. https://doi.org/10.1016/j.jece.2018.10.001
Zangeneh, H., Zinatizadeh, A. A., Feyzi, M., Zinadini, S., & Bahnemann, D. W. (2018). Photomineralization of recalcitrant wastewaters by a novel magnetically recyclable boron doped-TiO2-SiO2 cobalt ferrite nanocomposite as a visible-driven heterogeneous photocatalyst. Journal of Environmental Chemical Engineering, 6(5), 6370-6381. https://doi.org/10.1016/j.jece.2018.10.001
Zangeneh H, Zinatizadeh AA, Feyzi M, Zinadini S, Bahnemann DW. Photomineralization of recalcitrant wastewaters by a novel magnetically recyclable boron doped-TiO2-SiO2 cobalt ferrite nanocomposite as a visible-driven heterogeneous photocatalyst. Journal of Environmental Chemical Engineering. 2018 Okt;6(5):6370-6381. Epub 2018 Okt 2. doi: 10.1016/j.jece.2018.10.001
Zangeneh, H. ; Zinatizadeh, A.A. ; Feyzi, M. et al. / Photomineralization of recalcitrant wastewaters by a novel magnetically recyclable boron doped-TiO2-SiO2 cobalt ferrite nanocomposite as a visible-driven heterogeneous photocatalyst. in: Journal of Environmental Chemical Engineering. 2018 ; Jahrgang 6, Nr. 5. S. 6370-6381.
Download
@article{70e3323232ac4bde8c57caa522c82065,
title = "Photomineralization of recalcitrant wastewaters by a novel magnetically recyclable boron doped-TiO2-SiO2 cobalt ferrite nanocomposite as a visible-driven heterogeneous photocatalyst",
abstract = "In this work, different recalcitrant organic compounds including biologically treated palm oil mill effluent (POME), diazinon and paraquat dichloride and natural dye from algal growth in Solaymanshah's dam was degraded using a novel highly efficient magnetically visible driven photocatalyst (boron doped TiO 2-SiO 2 cobalt ferrite) which was synthesized by a sol gel hydrothermal method. The prepared nanocomposites were characterized by UV-vis diffuse reflectance (DRS) spectroscopy, X-ray diffraction (XRD), photoluminescence (PL), Fourier transform infrared (FT-IR), field emission scanning electron microscopy (FESEM) and vibrating sample magnetometer (VSM) analyses. The results revealed that boron doped-TiO 2-SiO 2 cobalt ferrite nanocomposite not only expanded the response region to the visible light but also reduced recombination of the photoinduced e -/h + pairs. The effects of various parameters, such as COD concentrations (300-800 mg/l), photocatalyst concentration (1.5-3.5 g/l) and pH (3-11) on the photocatalytic process were also evaluated. The COD contents was completely removed for the biologically treated POME, paraquat dichloride, diazinon, natural dye from algal growth in Solaymanshah dam's after 4/5, 3/5, 3 and 2/5 h, respectively at optimum conditions (initial COD concentration of 300 mg/l, catalyst loading 2/5 g/l and pH of 3). Furthermore, the magnetic nanocomposite can be easily recovered and separated with an extra magnet with a small loss of 0.01-0.05 g/l corresponding to 0.4-2 %. After being reused for three times, the reduction of COD removal efficiency of the natural dyes, diazinon, paraquat dichloride and biologically treated POME was about 1, 1, 3 and 4%, respectively that confirmed the photocatalytic stability of nanocomposite. ",
keywords = "Magnetic CoFe O nanoparticles, Recalcitrant compounds, Separable visible driven photocatalyst, Wastewater treatment under sun light",
author = "H. Zangeneh and A.A. Zinatizadeh and M. Feyzi and S. Zinadini and D.W. Bahnemann",
note = "Funding information: The authors would like to thank Kermanshah{\textquoteright}s Municipal Water and Wastewater Company (Grant no.: 14579/94/129 ) for their full financial support. The authors also thank the Razi University Research Council for support of this work.",
year = "2018",
month = oct,
doi = "10.1016/j.jece.2018.10.001",
language = "English",
volume = "6",
pages = "6370--6381",
number = "5",

}

Download

TY - JOUR

T1 - Photomineralization of recalcitrant wastewaters by a novel magnetically recyclable boron doped-TiO2-SiO2 cobalt ferrite nanocomposite as a visible-driven heterogeneous photocatalyst

AU - Zangeneh, H.

AU - Zinatizadeh, A.A.

AU - Feyzi, M.

AU - Zinadini, S.

AU - Bahnemann, D.W.

N1 - Funding information: The authors would like to thank Kermanshah’s Municipal Water and Wastewater Company (Grant no.: 14579/94/129 ) for their full financial support. The authors also thank the Razi University Research Council for support of this work.

PY - 2018/10

Y1 - 2018/10

N2 - In this work, different recalcitrant organic compounds including biologically treated palm oil mill effluent (POME), diazinon and paraquat dichloride and natural dye from algal growth in Solaymanshah's dam was degraded using a novel highly efficient magnetically visible driven photocatalyst (boron doped TiO 2-SiO 2 cobalt ferrite) which was synthesized by a sol gel hydrothermal method. The prepared nanocomposites were characterized by UV-vis diffuse reflectance (DRS) spectroscopy, X-ray diffraction (XRD), photoluminescence (PL), Fourier transform infrared (FT-IR), field emission scanning electron microscopy (FESEM) and vibrating sample magnetometer (VSM) analyses. The results revealed that boron doped-TiO 2-SiO 2 cobalt ferrite nanocomposite not only expanded the response region to the visible light but also reduced recombination of the photoinduced e -/h + pairs. The effects of various parameters, such as COD concentrations (300-800 mg/l), photocatalyst concentration (1.5-3.5 g/l) and pH (3-11) on the photocatalytic process were also evaluated. The COD contents was completely removed for the biologically treated POME, paraquat dichloride, diazinon, natural dye from algal growth in Solaymanshah dam's after 4/5, 3/5, 3 and 2/5 h, respectively at optimum conditions (initial COD concentration of 300 mg/l, catalyst loading 2/5 g/l and pH of 3). Furthermore, the magnetic nanocomposite can be easily recovered and separated with an extra magnet with a small loss of 0.01-0.05 g/l corresponding to 0.4-2 %. After being reused for three times, the reduction of COD removal efficiency of the natural dyes, diazinon, paraquat dichloride and biologically treated POME was about 1, 1, 3 and 4%, respectively that confirmed the photocatalytic stability of nanocomposite.

AB - In this work, different recalcitrant organic compounds including biologically treated palm oil mill effluent (POME), diazinon and paraquat dichloride and natural dye from algal growth in Solaymanshah's dam was degraded using a novel highly efficient magnetically visible driven photocatalyst (boron doped TiO 2-SiO 2 cobalt ferrite) which was synthesized by a sol gel hydrothermal method. The prepared nanocomposites were characterized by UV-vis diffuse reflectance (DRS) spectroscopy, X-ray diffraction (XRD), photoluminescence (PL), Fourier transform infrared (FT-IR), field emission scanning electron microscopy (FESEM) and vibrating sample magnetometer (VSM) analyses. The results revealed that boron doped-TiO 2-SiO 2 cobalt ferrite nanocomposite not only expanded the response region to the visible light but also reduced recombination of the photoinduced e -/h + pairs. The effects of various parameters, such as COD concentrations (300-800 mg/l), photocatalyst concentration (1.5-3.5 g/l) and pH (3-11) on the photocatalytic process were also evaluated. The COD contents was completely removed for the biologically treated POME, paraquat dichloride, diazinon, natural dye from algal growth in Solaymanshah dam's after 4/5, 3/5, 3 and 2/5 h, respectively at optimum conditions (initial COD concentration of 300 mg/l, catalyst loading 2/5 g/l and pH of 3). Furthermore, the magnetic nanocomposite can be easily recovered and separated with an extra magnet with a small loss of 0.01-0.05 g/l corresponding to 0.4-2 %. After being reused for three times, the reduction of COD removal efficiency of the natural dyes, diazinon, paraquat dichloride and biologically treated POME was about 1, 1, 3 and 4%, respectively that confirmed the photocatalytic stability of nanocomposite.

KW - Magnetic CoFe O nanoparticles

KW - Recalcitrant compounds

KW - Separable visible driven photocatalyst

KW - Wastewater treatment under sun light

UR - http://www.scopus.com/inward/record.url?scp=85054767135&partnerID=8YFLogxK

U2 - 10.1016/j.jece.2018.10.001

DO - 10.1016/j.jece.2018.10.001

M3 - Article

VL - 6

SP - 6370

EP - 6381

JO - Journal of Environmental Chemical Engineering

JF - Journal of Environmental Chemical Engineering

IS - 5

ER -