Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 2567-2576 |
| Seitenumfang | 10 |
| Fachzeitschrift | NANOSCALE |
| Jahrgang | 17 |
| Ausgabenummer | 5 |
| Publikationsstatus | Veröffentlicht - 20 Jan. 2025 |
Abstract
Loading cocatalysts on semiconductor-based photocatalysts to create active reaction sites is a preferable method to enhance photocatalytic activity and a widely adopted strategy to achieve effective photocatalytic applications. Although theoretical calculations suggest that the broad density of states of noble metal cocatalysts, such as Pt, act as a recombination center, this has never been experimentally demonstrated. Herein, we employed pico-nano and nano-micro second transient absorption spectroscopy to investigate the often overlooked photogenerated holes, instead of the widely studied electrons on Pt- and Ni-loaded SrTiO3 to evaluate the effects of cocatalysts as a recombination center. It is demonstrated that Pt serves as the recombination center with no sacrificial agent; recombination can be suppressed by a hole scavenger, while recombination is not significant on Ni with localized density of states. It is also found that photo-generated holes in SrTiO3 tend to migrate to Pt within 400 ps, and photo-generated holes generated in the bulk gradually migrate to Pt cocatalysts in a micro-second regime.
ASJC Scopus Sachgebiete
- Werkstoffwissenschaften (insg.)
- Allgemeine Materialwissenschaften
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in: NANOSCALE, Jahrgang 17, Nr. 5, 20.01.2025, S. 2567-2576.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Photogenerated charge carrier dynamics on Pt-loaded SrTiO3 nanoparticles studied via transient-absorption spectroscopy
AU - Ichihara, Fumihiko
AU - Pang, Hong
AU - Kako, Tetsuya
AU - Bahnemann, Detlef W.
AU - Ye, Jinhua
N1 - Publisher Copyright: © 2025 The Royal Society of Chemistry.
PY - 2025/1/20
Y1 - 2025/1/20
N2 - Loading cocatalysts on semiconductor-based photocatalysts to create active reaction sites is a preferable method to enhance photocatalytic activity and a widely adopted strategy to achieve effective photocatalytic applications. Although theoretical calculations suggest that the broad density of states of noble metal cocatalysts, such as Pt, act as a recombination center, this has never been experimentally demonstrated. Herein, we employed pico-nano and nano-micro second transient absorption spectroscopy to investigate the often overlooked photogenerated holes, instead of the widely studied electrons on Pt- and Ni-loaded SrTiO3 to evaluate the effects of cocatalysts as a recombination center. It is demonstrated that Pt serves as the recombination center with no sacrificial agent; recombination can be suppressed by a hole scavenger, while recombination is not significant on Ni with localized density of states. It is also found that photo-generated holes in SrTiO3 tend to migrate to Pt within 400 ps, and photo-generated holes generated in the bulk gradually migrate to Pt cocatalysts in a micro-second regime.
AB - Loading cocatalysts on semiconductor-based photocatalysts to create active reaction sites is a preferable method to enhance photocatalytic activity and a widely adopted strategy to achieve effective photocatalytic applications. Although theoretical calculations suggest that the broad density of states of noble metal cocatalysts, such as Pt, act as a recombination center, this has never been experimentally demonstrated. Herein, we employed pico-nano and nano-micro second transient absorption spectroscopy to investigate the often overlooked photogenerated holes, instead of the widely studied electrons on Pt- and Ni-loaded SrTiO3 to evaluate the effects of cocatalysts as a recombination center. It is demonstrated that Pt serves as the recombination center with no sacrificial agent; recombination can be suppressed by a hole scavenger, while recombination is not significant on Ni with localized density of states. It is also found that photo-generated holes in SrTiO3 tend to migrate to Pt within 400 ps, and photo-generated holes generated in the bulk gradually migrate to Pt cocatalysts in a micro-second regime.
UR - http://www.scopus.com/inward/record.url?scp=85215825198&partnerID=8YFLogxK
U2 - 10.1039/d4nr04725g
DO - 10.1039/d4nr04725g
M3 - Article
AN - SCOPUS:85215825198
VL - 17
SP - 2567
EP - 2576
JO - NANOSCALE
JF - NANOSCALE
SN - 2040-3364
IS - 5
ER -