Details
| Originalsprache | Englisch |
|---|---|
| Aufsatznummer | e202200701 |
| Fachzeitschrift | European Journal of Organic Chemistry |
| Jahrgang | 2022 |
| Ausgabenummer | 41 |
| Frühes Online-Datum | 9 Aug. 2022 |
| Publikationsstatus | Veröffentlicht - 2 Nov. 2022 |
Abstract
Photochemical, sigmatropic 1,3-acyl shifts represent a powerful tool to construct quaternary carbon atoms and the backbones of complex natural products which cannot be constructed easily by conventional methods. This review highlights applications of 1,3-acyl shifts to elegant, partly biomimetic total syntheses of natural products by discussing the underlying photochemical equilibrium.
ASJC Scopus Sachgebiete
- Chemie (insg.)
- Physikalische und Theoretische Chemie
- Chemie (insg.)
- Organische Chemie
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in: European Journal of Organic Chemistry, Jahrgang 2022, Nr. 41, e202200701, 02.11.2022.
Publikation: Beitrag in Fachzeitschrift › Übersichtsarbeit › Forschung › Peer-Review
}
TY - JOUR
T1 - Photochemical 1,3-Acyl Shifts in Natural Product Synthesis
AU - Lübken, Dennis
AU - Siekmeyer, Björn
AU - Kalesse, Markus
N1 - Funding Information: Open Access funding enabled and organized by Projekt DEAL.
PY - 2022/11/2
Y1 - 2022/11/2
N2 - Photochemical, sigmatropic 1,3-acyl shifts represent a powerful tool to construct quaternary carbon atoms and the backbones of complex natural products which cannot be constructed easily by conventional methods. This review highlights applications of 1,3-acyl shifts to elegant, partly biomimetic total syntheses of natural products by discussing the underlying photochemical equilibrium.
AB - Photochemical, sigmatropic 1,3-acyl shifts represent a powerful tool to construct quaternary carbon atoms and the backbones of complex natural products which cannot be constructed easily by conventional methods. This review highlights applications of 1,3-acyl shifts to elegant, partly biomimetic total syntheses of natural products by discussing the underlying photochemical equilibrium.
KW - 1,3-Acyl shift
KW - Natural products
KW - Photochemistry
KW - Terpenes
KW - Total synthesis
UR - http://www.scopus.com/inward/record.url?scp=85138431393&partnerID=8YFLogxK
U2 - 10.1002/ejoc.202200701
DO - 10.1002/ejoc.202200701
M3 - Review article
AN - SCOPUS:85138431393
VL - 2022
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
SN - 1434-193X
IS - 41
M1 - e202200701
ER -