TY - JOUR

T1 - Phase relations in the Cabeza de Araya cordierite monzogranite, Iberian Massif

T2 - Implications for the formation of cordierite in a crystal mush

AU - García-Moreno, O.

AU - Corretgé, L. G.

AU - Holtz, Francois

AU - García-Arias, M.

AU - Rodríguez, René Carlos

N1 - Funding Information: This work forms part of the PhD. thesis of Olga García-Moreno, with help of the Principado de Asturias by a predoctoral grant. Financial support for the experiments comes from the Spanish MEC and MCYT projects: PB97-0439, BTE2001-2769, LGC2004-06808-C04 as well as from the German Science Foundation (project HO1337/22). Carmen Rodriguez is grateful to her post-doctoral grant from the University of Huelva. We would like to thank Antonio Castro for the discussion about the phase relations and cordierite meaning in Cabeza de Araya rocks. Publisher Copyright: © O. García-Moreno, L.G. Corretgé, F. Holtz, M. García-Arias, C. Rodríguez, 2017 CC BY-SA. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.

PY - 2017

Y1 - 2017

N2 - Experimental investigations and thermodynamic calculations of the phase relations of a cordierite-rich monzogranite from the Cabeza de Araya batholith (Cáceres, Spain) have been performed to understand the formation of cordierite. The experiments failed to crystallize cordierite in the pressure range 200-600MPa, in the temperature range 700-975ºC and for different water activities (melt water contents between 2 and 6 wt.%). In contrast, clinopyroxene and orthopyroxene (absent in the natural mineral rock assemblage), together with biotite, were observed as ferromagnesian assemblage in a wide range of experimental conditions. Thermodynamic calculations, using the software PERPLE_X, describe the formation of cordierite only at 200 and 400MPa and very low water contents, and the amount of cordierite formed in the models is always below 3.5 vol.%. The results indicate that cordierite is not in equilibrium with the bulk rock compositions. The most probable explanation was that cordierite nucleated and crystallized from a melt that is not in equilibrium with part of the mineral assemblage present in the magma. This “non-reactive” mineral assemblage was mainly composed of plagioclase. The silicate melts from which cordierite crystallized was more Al-rich and K-rich than the silicate melt composition in equilibrium with the bulk composition. One possible process for the high Al content of the silicate melt is related to assimilation and partial melting of Al-rich metasediments. An exo-perictetic reaction is assumed to account for both textural and geochemical observations. On the other hand, hybridization processes typical for calc-alkaline series can also explain the high proportions of “non-reactive” minerals observed in relatively high temperature magmas. This study clearly demonstrates that silicate melts in a crystal mush can depart significantly from the composition of melt that should be in equilibrium with the bulk solid assemblage.

AB - Experimental investigations and thermodynamic calculations of the phase relations of a cordierite-rich monzogranite from the Cabeza de Araya batholith (Cáceres, Spain) have been performed to understand the formation of cordierite. The experiments failed to crystallize cordierite in the pressure range 200-600MPa, in the temperature range 700-975ºC and for different water activities (melt water contents between 2 and 6 wt.%). In contrast, clinopyroxene and orthopyroxene (absent in the natural mineral rock assemblage), together with biotite, were observed as ferromagnesian assemblage in a wide range of experimental conditions. Thermodynamic calculations, using the software PERPLE_X, describe the formation of cordierite only at 200 and 400MPa and very low water contents, and the amount of cordierite formed in the models is always below 3.5 vol.%. The results indicate that cordierite is not in equilibrium with the bulk rock compositions. The most probable explanation was that cordierite nucleated and crystallized from a melt that is not in equilibrium with part of the mineral assemblage present in the magma. This “non-reactive” mineral assemblage was mainly composed of plagioclase. The silicate melts from which cordierite crystallized was more Al-rich and K-rich than the silicate melt composition in equilibrium with the bulk composition. One possible process for the high Al content of the silicate melt is related to assimilation and partial melting of Al-rich metasediments. An exo-perictetic reaction is assumed to account for both textural and geochemical observations. On the other hand, hybridization processes typical for calc-alkaline series can also explain the high proportions of “non-reactive” minerals observed in relatively high temperature magmas. This study clearly demonstrates that silicate melts in a crystal mush can depart significantly from the composition of melt that should be in equilibrium with the bulk solid assemblage.

KW - Cordierite

KW - Monzogranites experimental petrology

KW - Peritectic

KW - Pseudosections

UR - http://www.scopus.com/inward/record.url?scp=85038416510&partnerID=8YFLogxK

U2 - 10.1344/GeologicaActa2017.15.4.6

DO - 10.1344/GeologicaActa2017.15.4.6

M3 - Article

AN - SCOPUS:85038416510

VL - 15

SP - 337

EP - 359

JO - Geologica Acta

JF - Geologica Acta

SN - 1695-6133

IS - 4

ER -