Parameterization and regionalization of Cd sorption characteristics of sandy soils. I. Freundlich type parameters

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Günther Springob
  • Jürgen Böttcher
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Details

OriginalspracheEnglisch
Seiten (von - bis)681-687
Seitenumfang7
FachzeitschriftJournal of Plant Nutrition and Soil Science
Jahrgang161
Ausgabenummer6
PublikationsstatusVeröffentlicht - 1998

Abstract

Cd sorption isotherms (n = 24) were established for arable, sandy-soils of the 'Fuhrberger Feld' catchment area northeast of Hannover (Germany) using 0.01 Mc Ca(NO3)2 solution with Cd additions ranging from 0 to 44 μMc Cd. Alternative fractions of initially (prior to analysis) sorbed Cd (S0) were added to the amount sorbed during the experiments. The Freundlich equation was fitted to the resulting isotherms. The obtained retention parameters k and M varied with respect to the different S0 fractions. Isotherms corrected with CdEDTA as S0 fraction were nonlinear in their log-form. The highest degree of log-linearity is obtained if S0 is characterized by 40% of the aqua regia extractable Cd. The corresponding k values ranged from 36 to 1275 g1-M LM kg-1 (mean 338 g1-M LM kg-1, cv = 92%). The Freundlich exponent M showed less variation (0.7 to 1.1, cv = 12%) with a mean of 0.88. Functions based on these parameters predicted Cd concentrations in Ca(NO3)2-soil suspensions well (r2 = 0.96) but were hardly related to Cd concentrations of 'fresh' soil solutions (r2 = 0.20).

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Parameterization and regionalization of Cd sorption characteristics of sandy soils. I. Freundlich type parameters. / Springob, Günther; Böttcher, Jürgen.
in: Journal of Plant Nutrition and Soil Science, Jahrgang 161, Nr. 6, 1998, S. 681-687.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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abstract = "Cd sorption isotherms (n = 24) were established for arable, sandy-soils of the 'Fuhrberger Feld' catchment area northeast of Hannover (Germany) using 0.01 Mc Ca(NO3)2 solution with Cd additions ranging from 0 to 44 μMc Cd. Alternative fractions of initially (prior to analysis) sorbed Cd (S0) were added to the amount sorbed during the experiments. The Freundlich equation was fitted to the resulting isotherms. The obtained retention parameters k and M varied with respect to the different S0 fractions. Isotherms corrected with CdEDTA as S0 fraction were nonlinear in their log-form. The highest degree of log-linearity is obtained if S0 is characterized by 40% of the aqua regia extractable Cd. The corresponding k values ranged from 36 to 1275 g1-M LM kg-1 (mean 338 g1-M LM kg-1, cv = 92%). The Freundlich exponent M showed less variation (0.7 to 1.1, cv = 12%) with a mean of 0.88. Functions based on these parameters predicted Cd concentrations in Ca(NO3)2-soil suspensions well (r2 = 0.96) but were hardly related to Cd concentrations of 'fresh' soil solutions (r2 = 0.20).",
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T1 - Parameterization and regionalization of Cd sorption characteristics of sandy soils. I. Freundlich type parameters

AU - Springob, Günther

AU - Böttcher, Jürgen

N1 - Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 1998

Y1 - 1998

N2 - Cd sorption isotherms (n = 24) were established for arable, sandy-soils of the 'Fuhrberger Feld' catchment area northeast of Hannover (Germany) using 0.01 Mc Ca(NO3)2 solution with Cd additions ranging from 0 to 44 μMc Cd. Alternative fractions of initially (prior to analysis) sorbed Cd (S0) were added to the amount sorbed during the experiments. The Freundlich equation was fitted to the resulting isotherms. The obtained retention parameters k and M varied with respect to the different S0 fractions. Isotherms corrected with CdEDTA as S0 fraction were nonlinear in their log-form. The highest degree of log-linearity is obtained if S0 is characterized by 40% of the aqua regia extractable Cd. The corresponding k values ranged from 36 to 1275 g1-M LM kg-1 (mean 338 g1-M LM kg-1, cv = 92%). The Freundlich exponent M showed less variation (0.7 to 1.1, cv = 12%) with a mean of 0.88. Functions based on these parameters predicted Cd concentrations in Ca(NO3)2-soil suspensions well (r2 = 0.96) but were hardly related to Cd concentrations of 'fresh' soil solutions (r2 = 0.20).

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