Oxide-Based Thermoelectric Generator for High-Temperature Application Using p-Type Ca3Co4O9 and n-Type In1.95Sn0.05O3 Legs

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Michael Bittner
  • Benjamin Geppert
  • Nikola Kanas
  • Sathya Prakash Singh
  • Kjell Wiik
  • Armin Feldhoff

Externe Organisationen

  • Norwegian University of Science and Technology (NTNU)
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Details

OriginalspracheEnglisch
Seiten (von - bis)213-222
Seitenumfang10
FachzeitschriftEnergy Harvesting and Systems
Jahrgang3
Ausgabenummer3
Frühes Online-Datum5 Apr. 2016
PublikationsstatusVeröffentlicht - 1 Aug. 2016

Abstract

A thermoelectric generator couples an entropy current with an electrical current in a way, that thermal energy is transformed to electrical energy. Hereby the thermoelectric energy conversion can be described in terms of fluxes of entropy and electric charge at locally different temperature and electric potential. Crucial for the function of a thermoelectric generator is the sign and strength of the coupling between the entropy current and the electrical current in the thermoelectric materials. For high-temperature application, tin-doped indium oxide (In1.95Sn0.05O3) and misfit-layered calcium cobalt oxide (Ca3Co4O9) ceramics were used as n- and p-type legs. The n-type material reaches a power factor of 6.8μW·cm-1·K-2 at 1,073 K and a figure of merit ZT of 0.07. The p-type material reaches 1.23μW·cm-1·K-2 and a figure of merit ZT of 0.21 at 1,073 K. A thermoelectric generator consisting of ten legs was characterized for different invested temperatures. It delivers 4.8 mW maximum power output and a electrical power density of 2.13mW×cm-2 when the hot side is at 1,073 K and a temperature difference of 113 K is applied.

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Oxide-Based Thermoelectric Generator for High-Temperature Application Using p-Type Ca3Co4O9 and n-Type In1.95Sn0.05O3 Legs. / Bittner, Michael; Geppert, Benjamin; Kanas, Nikola et al.
in: Energy Harvesting and Systems, Jahrgang 3, Nr. 3, 01.08.2016, S. 213-222.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Bittner, M, Geppert, B, Kanas, N, Singh, SP, Wiik, K & Feldhoff, A 2016, 'Oxide-Based Thermoelectric Generator for High-Temperature Application Using p-Type Ca3Co4O9 and n-Type In1.95Sn0.05O3 Legs', Energy Harvesting and Systems, Jg. 3, Nr. 3, S. 213-222. https://doi.org/10.1515/ehs-2016-0002
Bittner M, Geppert B, Kanas N, Singh SP, Wiik K, Feldhoff A. Oxide-Based Thermoelectric Generator for High-Temperature Application Using p-Type Ca3Co4O9 and n-Type In1.95Sn0.05O3 Legs. Energy Harvesting and Systems. 2016 Aug 1;3(3):213-222. Epub 2016 Apr 5. doi: 10.1515/ehs-2016-0002
Bittner, Michael ; Geppert, Benjamin ; Kanas, Nikola et al. / Oxide-Based Thermoelectric Generator for High-Temperature Application Using p-Type Ca3Co4O9 and n-Type In1.95Sn0.05O3 Legs. in: Energy Harvesting and Systems. 2016 ; Jahrgang 3, Nr. 3. S. 213-222.
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abstract = "A thermoelectric generator couples an entropy current with an electrical current in a way, that thermal energy is transformed to electrical energy. Hereby the thermoelectric energy conversion can be described in terms of fluxes of entropy and electric charge at locally different temperature and electric potential. Crucial for the function of a thermoelectric generator is the sign and strength of the coupling between the entropy current and the electrical current in the thermoelectric materials. For high-temperature application, tin-doped indium oxide (In1.95Sn0.05O3) and misfit-layered calcium cobalt oxide (Ca3Co4O9) ceramics were used as n- and p-type legs. The n-type material reaches a power factor of 6.8μW·cm-1·K-2 at 1,073 K and a figure of merit ZT of 0.07. The p-type material reaches 1.23μW·cm-1·K-2 and a figure of merit ZT of 0.21 at 1,073 K. A thermoelectric generator consisting of ten legs was characterized for different invested temperatures. It delivers 4.8 mW maximum power output and a electrical power density of 2.13mW×cm-2 when the hot side is at 1,073 K and a temperature difference of 113 K is applied.",
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AU - Geppert, Benjamin

AU - Kanas, Nikola

AU - Singh, Sathya Prakash

AU - Wiik, Kjell

AU - Feldhoff, Armin

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