Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups

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  • The University of Hong Kong
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OriginalspracheEnglisch
Aufsatznummerss-2016-z0440-op
Seiten (von - bis)145-150
Seitenumfang6
FachzeitschriftSynthesis (Germany)
Jahrgang49
Ausgabenummer1
PublikationsstatusVeröffentlicht - 3 Jan. 2017

Abstract

A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.

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Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups. / Ceylan, Sascha; Law, Henry Chun Hin; Kirschning, Andreas et al.
in: Synthesis (Germany), Jahrgang 49, Nr. 1, ss-2016-z0440-op, 03.01.2017, S. 145-150.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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abstract = "A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.",
keywords = "flow chemistry, organocatalysis, phenols, phosphine, polymer-supported catalyst, rearrangement",
author = "Sascha Ceylan and Law, {Henry Chun Hin} and Andreas Kirschning and Toy, {Patrick H.}",
note = "Funding information: This research was funded in part by the Research Grants Council of the Hong Kong S. A. R., P. R. of China (Project No. HKU 704108P and GHK 031/07), and the Deutscher Akademischer Austauschdienst (DAAD).",
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T1 - Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups

AU - Ceylan, Sascha

AU - Law, Henry Chun Hin

AU - Kirschning, Andreas

AU - Toy, Patrick H.

N1 - Funding information: This research was funded in part by the Research Grants Council of the Hong Kong S. A. R., P. R. of China (Project No. HKU 704108P and GHK 031/07), and the Deutscher Akademischer Austauschdienst (DAAD).

PY - 2017/1/3

Y1 - 2017/1/3

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AB - A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.

KW - flow chemistry

KW - organocatalysis

KW - phenols

KW - phosphine

KW - polymer-supported catalyst

KW - rearrangement

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U2 - 10.1055/s-0036-1588589

DO - 10.1055/s-0036-1588589

M3 - Article

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SP - 145

EP - 150

JO - Synthesis (Germany)

JF - Synthesis (Germany)

SN - 0039-7881

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M1 - ss-2016-z0440-op

ER -

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