Novel Tricarbonyl(η4‐dihydroacepentalene)iron Complexes and Tricarbonyl(η2‐dihydroacepentalene)ferrates(−2)

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Titel in ÜbersetzungNeuartige Tricarbonyl(η4-dihydroacepentalen)eisen-Komplexe und Tricarbonyl-(η2-dihydroacepentalen)ferrate( — 2)
OriginalspracheEnglisch
Seiten (von - bis)707-708
Seitenumfang2
FachzeitschriftAngewandte Chemie International Edition in English
Jahrgang23
Ausgabenummer9
PublikationsstatusVeröffentlicht - Sept. 1984
Extern publiziertJa

Abstract

The first spectroscopically characterized (η2‐olefin)ferrates( – 2), 3, are formed on reduction of the novel (η4‐diene)iron complexes 2 with sodium. This reaction proceeds via a radical anion; high spin density at the iron is detected by ESR spectroscopy in the case of the reduction product of 2, NR2 = piperidino. (Figure Presented.)

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Novel Tricarbonyl(η4‐dihydroacepentalene)iron Complexes and Tricarbonyl(η2‐dihydroacepentalene)ferrates(−2). / Butenschön, Holger; de Meijere, Armin.
in: Angewandte Chemie International Edition in English, Jahrgang 23, Nr. 9, 09.1984, S. 707-708.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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abstract = "The first spectroscopically characterized (η2‐olefin)ferrates( – 2), 3, are formed on reduction of the novel (η4‐diene)iron complexes 2 with sodium. This reaction proceeds via a radical anion; high spin density at the iron is detected by ESR spectroscopy in the case of the reduction product of 2, NR2 = piperidino. (Figure Presented.)",
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