Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 3465-3470 |
| Seitenumfang | 6 |
| Fachzeitschrift | Angewandte Chemie - International Edition |
| Jahrgang | 45 |
| Ausgabenummer | 21 |
| Publikationsstatus | Veröffentlicht - 19 Mai 2006 |
Abstract
Light at the end of the tunnel: Knowledge of the feasible tunneling pathways of a molecule can shed light on the interaction mechanisms that govern its internal dynamics. A combination of rotational spectroscopy, permutation inversion group theory, and multidimensional tunneling formalism has shown that in the series (CH3)3XCI (X = Si, Ge, Sn), electrostatic repulsion is gradually reduced and the chemical bond gains importance. (Figure Presented).
ASJC Scopus Sachgebiete
- Chemische Verfahrenstechnik (insg.)
- Katalyse
- Chemie (insg.)
- Allgemeine Chemie
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in: Angewandte Chemie - International Edition, Jahrgang 45, Nr. 21, 19.05.2006, S. 3465-3470.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Multidimensional large-amplitude motion
T2 - Revealing concurrent tunneling pathways in molecules with several internal rotors
AU - Schnell, Melanie
AU - Grabow, Jens Uwe
PY - 2006/5/19
Y1 - 2006/5/19
N2 - Light at the end of the tunnel: Knowledge of the feasible tunneling pathways of a molecule can shed light on the interaction mechanisms that govern its internal dynamics. A combination of rotational spectroscopy, permutation inversion group theory, and multidimensional tunneling formalism has shown that in the series (CH3)3XCI (X = Si, Ge, Sn), electrostatic repulsion is gradually reduced and the chemical bond gains importance. (Figure Presented).
AB - Light at the end of the tunnel: Knowledge of the feasible tunneling pathways of a molecule can shed light on the interaction mechanisms that govern its internal dynamics. A combination of rotational spectroscopy, permutation inversion group theory, and multidimensional tunneling formalism has shown that in the series (CH3)3XCI (X = Si, Ge, Sn), electrostatic repulsion is gradually reduced and the chemical bond gains importance. (Figure Presented).
KW - Microwave spectroscopy
KW - Molecular dynamics
KW - Nuclear quadrupole coupling
KW - Theoretical chemistry
UR - http://www.scopus.com/inward/record.url?scp=33746217415&partnerID=8YFLogxK
U2 - 10.1002/anie.200600201
DO - 10.1002/anie.200600201
M3 - Article
AN - SCOPUS:33746217415
VL - 45
SP - 3465
EP - 3470
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 21
ER -