Modeling the generation and dissociation of the boron-oxygen complex in B-Doped Cz-Si

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

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  • Institut für Solarenergieforschung GmbH (ISFH)
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OriginalspracheEnglisch
Titel des Sammelwerks33rd IEEE Photovoltaic Specialists Conference, PVSC 2008
PublikationsstatusVeröffentlicht - 2008
Extern publiziertJa
Veranstaltung33rd IEEE Photovoltaic Specialists Conference, PVSC 2008 - San Diego, CA, USA / Vereinigte Staaten
Dauer: 11 Mai 200816 Mai 2008

Publikationsreihe

NameConference Record of the IEEE Photovoltaic Specialists Conference
ISSN (Print)0160-8371

Abstract

We demonstrate that the boron-oxygen (BsO2i) recombination center responsible for the light-induced degradation of Czochralski silicon solar cells can be deactivated by simultaneous annealing and illumination. After applying this deactivation treatment the improved carrier lifetime is shown to be stable under illumination at room temperature. The measured dependence of the deactivation rate as a function of temperature indicates that the process is thermally activated. Based on the experimental findings a defect reaction model is proposed which attributes the deactivation to a dissociation reaction of a complex XY of unknown composition and to the subsequent association of one component X of this complex with the oxygen dimer O2i into XO2i, thereby reducing the concentration of unbound O2i. An excellent agreement between the experimental and the modeled time dependence of the BsO2i concentration is found.

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Modeling the generation and dissociation of the boron-oxygen complex in B-Doped Cz-Si. / Lim, Bianca; Bothe, Karsten; Schmidt, Jan.
33rd IEEE Photovoltaic Specialists Conference, PVSC 2008. 2008. 4922482 (Conference Record of the IEEE Photovoltaic Specialists Conference).

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Lim, B, Bothe, K & Schmidt, J 2008, Modeling the generation and dissociation of the boron-oxygen complex in B-Doped Cz-Si. in 33rd IEEE Photovoltaic Specialists Conference, PVSC 2008., 4922482, Conference Record of the IEEE Photovoltaic Specialists Conference, 33rd IEEE Photovoltaic Specialists Conference, PVSC 2008, San Diego, CA, USA / Vereinigte Staaten, 11 Mai 2008. https://doi.org/10.1109/PVSC.2008.4922482
Lim, B., Bothe, K., & Schmidt, J. (2008). Modeling the generation and dissociation of the boron-oxygen complex in B-Doped Cz-Si. In 33rd IEEE Photovoltaic Specialists Conference, PVSC 2008 Artikel 4922482 (Conference Record of the IEEE Photovoltaic Specialists Conference). https://doi.org/10.1109/PVSC.2008.4922482
Lim B, Bothe K, Schmidt J. Modeling the generation and dissociation of the boron-oxygen complex in B-Doped Cz-Si. in 33rd IEEE Photovoltaic Specialists Conference, PVSC 2008. 2008. 4922482. (Conference Record of the IEEE Photovoltaic Specialists Conference). doi: 10.1109/PVSC.2008.4922482
Lim, Bianca ; Bothe, Karsten ; Schmidt, Jan. / Modeling the generation and dissociation of the boron-oxygen complex in B-Doped Cz-Si. 33rd IEEE Photovoltaic Specialists Conference, PVSC 2008. 2008. (Conference Record of the IEEE Photovoltaic Specialists Conference).
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AU - Bothe, Karsten

AU - Schmidt, Jan

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Y1 - 2008

N2 - We demonstrate that the boron-oxygen (BsO2i) recombination center responsible for the light-induced degradation of Czochralski silicon solar cells can be deactivated by simultaneous annealing and illumination. After applying this deactivation treatment the improved carrier lifetime is shown to be stable under illumination at room temperature. The measured dependence of the deactivation rate as a function of temperature indicates that the process is thermally activated. Based on the experimental findings a defect reaction model is proposed which attributes the deactivation to a dissociation reaction of a complex XY of unknown composition and to the subsequent association of one component X of this complex with the oxygen dimer O2i into XO2i, thereby reducing the concentration of unbound O2i. An excellent agreement between the experimental and the modeled time dependence of the BsO2i concentration is found.

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