Microwave-assisted Suzuki-Miyaura reactions with an insoluble pyridine-aldoxime Pd-catalyst

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OriginalspracheEnglisch
Seiten (von - bis)1699-1702
Seitenumfang4
FachzeitschriftSynlett
Ausgabenummer10
PublikationsstatusVeröffentlicht - 15 Juli 2004

Abstract

The preparation of a solid Pd(II)-precatalyst and its use in microwave-assisted Suzuki-Miyaura reactions in water is described. The precatalyst is obtained by treatment of 4-pyridine-aldoxime with Na 2PdCl4 and is insoluble in organic solvents as well as in water. Its robustness under microwave conditions and its insolubility allows simple reuse in 'teabags'.

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Microwave-assisted Suzuki-Miyaura reactions with an insoluble pyridine-aldoxime Pd-catalyst. / Solodenko, Wladimir; Schön, Uwe; Messinger, Josef et al.
in: Synlett, Nr. 10, 15.07.2004, S. 1699-1702.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Solodenko W, Schön U, Messinger J, Glinschert A, Kirschning A. Microwave-assisted Suzuki-Miyaura reactions with an insoluble pyridine-aldoxime Pd-catalyst. Synlett. 2004 Jul 15;(10):1699-1702. doi: 10.1055/s-2004-829546
Solodenko, Wladimir ; Schön, Uwe ; Messinger, Josef et al. / Microwave-assisted Suzuki-Miyaura reactions with an insoluble pyridine-aldoxime Pd-catalyst. in: Synlett. 2004 ; Nr. 10. S. 1699-1702.
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AU - Schön, Uwe

AU - Messinger, Josef

AU - Glinschert, Anja

AU - Kirschning, Andreas

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N2 - The preparation of a solid Pd(II)-precatalyst and its use in microwave-assisted Suzuki-Miyaura reactions in water is described. The precatalyst is obtained by treatment of 4-pyridine-aldoxime with Na 2PdCl4 and is insoluble in organic solvents as well as in water. Its robustness under microwave conditions and its insolubility allows simple reuse in 'teabags'.

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