Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 278-286 |
| Seitenumfang | 9 |
| Fachzeitschrift | Journal of molecular spectroscopy |
| Jahrgang | 158 |
| Ausgabenummer | 2 |
| Publikationsstatus | Veröffentlicht - Apr. 1993 |
| Extern publiziert | Ja |
Abstract
Using a pulsed molecular beam microwave Fourier transform spectrometer, we measured the rotational spectrum of the 1,2-difluorobenzene-argon van der Waals complex in the range from 7 to 18 GHz. The rotational and centrifugal distortion constants were found to be A = l373.49072(9) MHz, B = 923.31007(10) MHz, C = 831.07477(6) MHz, ΔJ = 2.1104(8) kHz, ΔJK = 2.372(3) kHz, ΔK = -1.911(3) kHz. δJ = 0.4744(4) kHz, and δK = 1.785(9) kHz. The argon atom is placed 3.543 Å above the ring plane.
ASJC Scopus Sachgebiete
- Physik und Astronomie (insg.)
- Atom- und Molekularphysik sowie Optik
- Chemie (insg.)
- Spektroskopie
- Chemie (insg.)
- Physikalische und Theoretische Chemie
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in: Journal of molecular spectroscopy, Jahrgang 158, Nr. 2, 04.1993, S. 278-286.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Microwave Spectrum and Structure of the 1,2-Difluorobenzene-Argon van der Waals Complex
AU - Jochims, E.
AU - Grabow, J. U.
AU - Stahl, W.
PY - 1993/4
Y1 - 1993/4
N2 - Using a pulsed molecular beam microwave Fourier transform spectrometer, we measured the rotational spectrum of the 1,2-difluorobenzene-argon van der Waals complex in the range from 7 to 18 GHz. The rotational and centrifugal distortion constants were found to be A = l373.49072(9) MHz, B = 923.31007(10) MHz, C = 831.07477(6) MHz, ΔJ = 2.1104(8) kHz, ΔJK = 2.372(3) kHz, ΔK = -1.911(3) kHz. δJ = 0.4744(4) kHz, and δK = 1.785(9) kHz. The argon atom is placed 3.543 Å above the ring plane.
AB - Using a pulsed molecular beam microwave Fourier transform spectrometer, we measured the rotational spectrum of the 1,2-difluorobenzene-argon van der Waals complex in the range from 7 to 18 GHz. The rotational and centrifugal distortion constants were found to be A = l373.49072(9) MHz, B = 923.31007(10) MHz, C = 831.07477(6) MHz, ΔJ = 2.1104(8) kHz, ΔJK = 2.372(3) kHz, ΔK = -1.911(3) kHz. δJ = 0.4744(4) kHz, and δK = 1.785(9) kHz. The argon atom is placed 3.543 Å above the ring plane.
UR - http://www.scopus.com/inward/record.url?scp=43949171683&partnerID=8YFLogxK
U2 - 10.1006/jmsp.1993.1072
DO - 10.1006/jmsp.1993.1072
M3 - Article
AN - SCOPUS:43949171683
VL - 158
SP - 278
EP - 286
JO - Journal of molecular spectroscopy
JF - Journal of molecular spectroscopy
SN - 0022-2852
IS - 2
ER -