Details
Originalsprache | Englisch |
---|---|
Seiten (von - bis) | 64-69 |
Seitenumfang | 6 |
Fachzeitschrift | Chemical physics letters |
Jahrgang | 395 |
Ausgabenummer | 1-3 |
Frühes Online-Datum | 6 Aug. 2004 |
Publikationsstatus | Veröffentlicht - 1 Sept. 2004 |
Abstract
The effect of preadsorbed potassium on the pattern forming NO+H2 reaction on Rh(110) has been studied in the 10-7 mbar range using photoelectron emission microscopy (PEEM) and scanning photoelectron microscopy (SPEM) as spatially resolving methods. Domain patterns of travelling wave fragments develop with pulses in adjacent domains moving in opposite directions parallel to the [11̄0] direction. 2D-elemental maps from in situ SPEM measurements show that potassium is concentrated in the oxygen covered part of the pattern whereas the nitrogen covered parts are largely free of potassium.
ASJC Scopus Sachgebiete
- Physik und Astronomie (insg.)
- Allgemeine Physik und Astronomie
- Chemie (insg.)
- Physikalische und Theoretische Chemie
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in: Chemical physics letters, Jahrgang 395, Nr. 1-3, 01.09.2004, S. 64-69.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Mass transport of alkali metal with pulses
T2 - Catalytic NO reduction with hydrogen on Rh(1 1 0)/K
AU - Marbach, H.
AU - Günther, S.
AU - Neubrand, T.
AU - Imbihl, R.
PY - 2004/9/1
Y1 - 2004/9/1
N2 - The effect of preadsorbed potassium on the pattern forming NO+H2 reaction on Rh(110) has been studied in the 10-7 mbar range using photoelectron emission microscopy (PEEM) and scanning photoelectron microscopy (SPEM) as spatially resolving methods. Domain patterns of travelling wave fragments develop with pulses in adjacent domains moving in opposite directions parallel to the [11̄0] direction. 2D-elemental maps from in situ SPEM measurements show that potassium is concentrated in the oxygen covered part of the pattern whereas the nitrogen covered parts are largely free of potassium.
AB - The effect of preadsorbed potassium on the pattern forming NO+H2 reaction on Rh(110) has been studied in the 10-7 mbar range using photoelectron emission microscopy (PEEM) and scanning photoelectron microscopy (SPEM) as spatially resolving methods. Domain patterns of travelling wave fragments develop with pulses in adjacent domains moving in opposite directions parallel to the [11̄0] direction. 2D-elemental maps from in situ SPEM measurements show that potassium is concentrated in the oxygen covered part of the pattern whereas the nitrogen covered parts are largely free of potassium.
UR - http://www.scopus.com/inward/record.url?scp=4344713295&partnerID=8YFLogxK
U2 - 10.1016/j.cplett.2004.05.124
DO - 10.1016/j.cplett.2004.05.124
M3 - Article
AN - SCOPUS:4344713295
VL - 395
SP - 64
EP - 69
JO - Chemical physics letters
JF - Chemical physics letters
SN - 0009-2614
IS - 1-3
ER -