Long-range coupling of adsorbates and its modifications on anisotropic metal surfaces

Publikation: Beitrag in FachzeitschriftKonferenzaufsatz in FachzeitschriftForschungPeer-Review

Autoren

Organisationseinheiten

Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)133-140
Seitenumfang8
FachzeitschriftVacuum
Jahrgang74
Ausgabenummer2
PublikationsstatusVeröffentlicht - 20 Feb. 2004
VeranstaltungInternational Workshop on Surface Physics - Polanica Zdroj, Polen
Dauer: 13 Sept. 200315 Sept. 2003

Abstract

Coupling over large distances up to nine lattice constants of (n × 1) chain structures, formed by alkali and alkaline earth metals on anisotropic surfaces like Mo(1 1 2), occurs mainly by adsorbate-induced Friedel oscillations of the electron system at the surface. We briefly review evidence for this mechanism. It causes wave-like modulations in the adsorbate-induced lateral relaxations in the systems Li/Mo(1 1 2) and Sr/Mo(1 1 2), found by LEED-IV analysis. Within this coupling mechanism the depinning transitions of the low coverage p(8 × 1) and p(5 × 1) chain structures of the Sr/Mo(1 1 2) system can be described semi-quantitatively. The collective nature of coupling is demonstrated by adding small amounts of electronegative impurities (oxygen atoms) at concentrations far below one atom per unit cell. These impurities are able to change periodicities and symmetries as well as stabilities of structures, and partly suppress phase transitions. The complexity of these phenomena goes beyond descriptions by the simple one-dimensional coupling mechanism.

ASJC Scopus Sachgebiete

Zitieren

Long-range coupling of adsorbates and its modifications on anisotropic metal surfaces. / Pfnür, Herbert; Godzik, G.; Block, Thomas.
in: Vacuum, Jahrgang 74, Nr. 2, 20.02.2004, S. 133-140.

Publikation: Beitrag in FachzeitschriftKonferenzaufsatz in FachzeitschriftForschungPeer-Review

Pfnür H, Godzik G, Block T. Long-range coupling of adsorbates and its modifications on anisotropic metal surfaces. Vacuum. 2004 Feb 20;74(2):133-140. doi: 10.1016/j.vacuum.2003.12.110
Pfnür, Herbert ; Godzik, G. ; Block, Thomas. / Long-range coupling of adsorbates and its modifications on anisotropic metal surfaces. in: Vacuum. 2004 ; Jahrgang 74, Nr. 2. S. 133-140.
Download
@article{2929e33182c7445aaf58cfd0c838ef93,
title = "Long-range coupling of adsorbates and its modifications on anisotropic metal surfaces",
abstract = "Coupling over large distances up to nine lattice constants of (n × 1) chain structures, formed by alkali and alkaline earth metals on anisotropic surfaces like Mo(1 1 2), occurs mainly by adsorbate-induced Friedel oscillations of the electron system at the surface. We briefly review evidence for this mechanism. It causes wave-like modulations in the adsorbate-induced lateral relaxations in the systems Li/Mo(1 1 2) and Sr/Mo(1 1 2), found by LEED-IV analysis. Within this coupling mechanism the depinning transitions of the low coverage p(8 × 1) and p(5 × 1) chain structures of the Sr/Mo(1 1 2) system can be described semi-quantitatively. The collective nature of coupling is demonstrated by adding small amounts of electronegative impurities (oxygen atoms) at concentrations far below one atom per unit cell. These impurities are able to change periodicities and symmetries as well as stabilities of structures, and partly suppress phase transitions. The complexity of these phenomena goes beyond descriptions by the simple one-dimensional coupling mechanism.",
keywords = "Impurities, Low-energy electron diffraction, Phase transitions, Two-dimensional systems",
author = "Herbert Pfn{\"u}r and G. Godzik and Thomas Block",
year = "2004",
month = feb,
day = "20",
doi = "10.1016/j.vacuum.2003.12.110",
language = "English",
volume = "74",
pages = "133--140",
journal = "Vacuum",
issn = "0042-207X",
publisher = "Elsevier Ltd.",
number = "2",
note = "International Workshop on Surface Physics ; Conference date: 13-09-2003 Through 15-09-2003",

}

Download

TY - JOUR

T1 - Long-range coupling of adsorbates and its modifications on anisotropic metal surfaces

AU - Pfnür, Herbert

AU - Godzik, G.

AU - Block, Thomas

PY - 2004/2/20

Y1 - 2004/2/20

N2 - Coupling over large distances up to nine lattice constants of (n × 1) chain structures, formed by alkali and alkaline earth metals on anisotropic surfaces like Mo(1 1 2), occurs mainly by adsorbate-induced Friedel oscillations of the electron system at the surface. We briefly review evidence for this mechanism. It causes wave-like modulations in the adsorbate-induced lateral relaxations in the systems Li/Mo(1 1 2) and Sr/Mo(1 1 2), found by LEED-IV analysis. Within this coupling mechanism the depinning transitions of the low coverage p(8 × 1) and p(5 × 1) chain structures of the Sr/Mo(1 1 2) system can be described semi-quantitatively. The collective nature of coupling is demonstrated by adding small amounts of electronegative impurities (oxygen atoms) at concentrations far below one atom per unit cell. These impurities are able to change periodicities and symmetries as well as stabilities of structures, and partly suppress phase transitions. The complexity of these phenomena goes beyond descriptions by the simple one-dimensional coupling mechanism.

AB - Coupling over large distances up to nine lattice constants of (n × 1) chain structures, formed by alkali and alkaline earth metals on anisotropic surfaces like Mo(1 1 2), occurs mainly by adsorbate-induced Friedel oscillations of the electron system at the surface. We briefly review evidence for this mechanism. It causes wave-like modulations in the adsorbate-induced lateral relaxations in the systems Li/Mo(1 1 2) and Sr/Mo(1 1 2), found by LEED-IV analysis. Within this coupling mechanism the depinning transitions of the low coverage p(8 × 1) and p(5 × 1) chain structures of the Sr/Mo(1 1 2) system can be described semi-quantitatively. The collective nature of coupling is demonstrated by adding small amounts of electronegative impurities (oxygen atoms) at concentrations far below one atom per unit cell. These impurities are able to change periodicities and symmetries as well as stabilities of structures, and partly suppress phase transitions. The complexity of these phenomena goes beyond descriptions by the simple one-dimensional coupling mechanism.

KW - Impurities

KW - Low-energy electron diffraction

KW - Phase transitions

KW - Two-dimensional systems

UR - http://www.scopus.com/inward/record.url?scp=2342630028&partnerID=8YFLogxK

U2 - 10.1016/j.vacuum.2003.12.110

DO - 10.1016/j.vacuum.2003.12.110

M3 - Conference article

AN - SCOPUS:2342630028

VL - 74

SP - 133

EP - 140

JO - Vacuum

JF - Vacuum

SN - 0042-207X

IS - 2

T2 - International Workshop on Surface Physics

Y2 - 13 September 2003 through 15 September 2003

ER -

Von denselben Autoren