LMU-3: A new cobalt aluminophosphate with exclusively five-coordinated aluminium and octahedrally coordinated cobalt

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Christian Panz
  • Kurt Polborn
  • Peter Behrens

Externe Organisationen

  • Ludwig-Maximilians-Universität München (LMU)
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)73-82
Seitenumfang10
FachzeitschriftInorganica chimica acta
Jahrgang269
Ausgabenummer1
PublikationsstatusVeröffentlicht - 20 Apr. 1998
Extern publiziertJa

Abstract

A new cobalt aluminophosphate, named LMU-3, has been synthesized from a synthesis mixture containing the 1,1'-dimethylcobalticinium complex cation as a cobalt source. Although the yield of the compound is very low, single crystals can be obtained and a crystal structure analysis has been carried out. The structure of LMU-3 is related to that of a nickel aluminophosphate with the formula K[Ni(H2O)2Al2(PO4)3]. It possesses an open framework built up from distorted [CoO6] octahedra, [AlO5] trigonal byramids and [PO4] tetrahedra. The still somewhat tentative formula for LMU-3 is NH4[Co(H2O)2Al2P3O 12]. It crystallizes in the monoclinic space group C2/c (No. 15) with a = 13.110(2), b=10.163(15), c=8.7424(14) Å, β=108.830(13)°, V=1102.8 Å3 and Z=4. The small amounts of LMU-3 available hamper further characterization.

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LMU-3: A new cobalt aluminophosphate with exclusively five-coordinated aluminium and octahedrally coordinated cobalt. / Panz, Christian; Polborn, Kurt; Behrens, Peter.
in: Inorganica chimica acta, Jahrgang 269, Nr. 1, 20.04.1998, S. 73-82.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Panz C, Polborn K, Behrens P. LMU-3: A new cobalt aluminophosphate with exclusively five-coordinated aluminium and octahedrally coordinated cobalt. Inorganica chimica acta. 1998 Apr 20;269(1):73-82. doi: 10.1016/S0020-1693(97)05772-1
Panz, Christian ; Polborn, Kurt ; Behrens, Peter. / LMU-3 : A new cobalt aluminophosphate with exclusively five-coordinated aluminium and octahedrally coordinated cobalt. in: Inorganica chimica acta. 1998 ; Jahrgang 269, Nr. 1. S. 73-82.
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abstract = "A new cobalt aluminophosphate, named LMU-3, has been synthesized from a synthesis mixture containing the 1,1'-dimethylcobalticinium complex cation as a cobalt source. Although the yield of the compound is very low, single crystals can be obtained and a crystal structure analysis has been carried out. The structure of LMU-3 is related to that of a nickel aluminophosphate with the formula K[Ni(H2O)2Al2(PO4)3]. It possesses an open framework built up from distorted [CoO6] octahedra, [AlO5] trigonal byramids and [PO4] tetrahedra. The still somewhat tentative formula for LMU-3 is NH4[Co(H2O)2Al2P3O 12]. It crystallizes in the monoclinic space group C2/c (No. 15) with a = 13.110(2), b=10.163(15), c=8.7424(14) {\AA}, β=108.830(13)°, V=1102.8 {\AA}3 and Z=4. The small amounts of LMU-3 available hamper further characterization.",
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T2 - A new cobalt aluminophosphate with exclusively five-coordinated aluminium and octahedrally coordinated cobalt

AU - Panz, Christian

AU - Polborn, Kurt

AU - Behrens, Peter

N1 - Funding information: We thank A. Glaue and A.M. Schneider (Munich) for their assistance and enlightening discussions as well as G. Wildermuth and J. Felsche (University of Konstanz) for the thermoanalyticai investigations. This work was supported by the Fends der Chemischen Industrie and the Riedel-de Haen-Sit flung.

PY - 1998/4/20

Y1 - 1998/4/20

N2 - A new cobalt aluminophosphate, named LMU-3, has been synthesized from a synthesis mixture containing the 1,1'-dimethylcobalticinium complex cation as a cobalt source. Although the yield of the compound is very low, single crystals can be obtained and a crystal structure analysis has been carried out. The structure of LMU-3 is related to that of a nickel aluminophosphate with the formula K[Ni(H2O)2Al2(PO4)3]. It possesses an open framework built up from distorted [CoO6] octahedra, [AlO5] trigonal byramids and [PO4] tetrahedra. The still somewhat tentative formula for LMU-3 is NH4[Co(H2O)2Al2P3O 12]. It crystallizes in the monoclinic space group C2/c (No. 15) with a = 13.110(2), b=10.163(15), c=8.7424(14) Å, β=108.830(13)°, V=1102.8 Å3 and Z=4. The small amounts of LMU-3 available hamper further characterization.

AB - A new cobalt aluminophosphate, named LMU-3, has been synthesized from a synthesis mixture containing the 1,1'-dimethylcobalticinium complex cation as a cobalt source. Although the yield of the compound is very low, single crystals can be obtained and a crystal structure analysis has been carried out. The structure of LMU-3 is related to that of a nickel aluminophosphate with the formula K[Ni(H2O)2Al2(PO4)3]. It possesses an open framework built up from distorted [CoO6] octahedra, [AlO5] trigonal byramids and [PO4] tetrahedra. The still somewhat tentative formula for LMU-3 is NH4[Co(H2O)2Al2P3O 12]. It crystallizes in the monoclinic space group C2/c (No. 15) with a = 13.110(2), b=10.163(15), c=8.7424(14) Å, β=108.830(13)°, V=1102.8 Å3 and Z=4. The small amounts of LMU-3 available hamper further characterization.

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