Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 525-527 |
| Seitenumfang | 3 |
| Fachzeitschrift | Synlett |
| Ausgabenummer | 3 |
| Publikationsstatus | Veröffentlicht - 2002 |
Abstract
Aldehydes are homologated to the corresponding α-hydroxy methyl esters using lithiated dimethoxymethyl diphenyl phosphine oxide. The primary addition product of this Horner-Wittig process collapses to the corresponding α-hydroxy ester under proton-catalyzed conditions.
ASJC Scopus Sachgebiete
- Chemie (insg.)
- Organische Chemie
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in: Synlett, Nr. 3, 2002, S. 525-527.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Lithiated dimethoxymethyl diphenyl phosphine oxide, a versatile formiate carbanion equivalent
AU - Monenschein, Holger
AU - Brünjes, Marco
AU - Kirschning, Andreas
PY - 2002
Y1 - 2002
N2 - Aldehydes are homologated to the corresponding α-hydroxy methyl esters using lithiated dimethoxymethyl diphenyl phosphine oxide. The primary addition product of this Horner-Wittig process collapses to the corresponding α-hydroxy ester under proton-catalyzed conditions.
AB - Aldehydes are homologated to the corresponding α-hydroxy methyl esters using lithiated dimethoxymethyl diphenyl phosphine oxide. The primary addition product of this Horner-Wittig process collapses to the corresponding α-hydroxy ester under proton-catalyzed conditions.
KW - Aldehydes
KW - Amino aldehydes
KW - Carbanions
KW - Hydrolyses
KW - Wittig reactions
UR - http://www.scopus.com/inward/record.url?scp=0036186009&partnerID=8YFLogxK
U2 - 10.1055/s-2002-20486
DO - 10.1055/s-2002-20486
M3 - Article
AN - SCOPUS:0036186009
SP - 525
EP - 527
JO - Synlett
JF - Synlett
SN - 0936-5214
IS - 3
ER -