Lifetime-degrading boron-oxygen centres in p-type and n-type compensated silicon

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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  • MEMC Electronic Materials
  • Institut für Solarenergieforschung GmbH (ISFH)
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OriginalspracheEnglisch
Aufsatznummer063515
FachzeitschriftJournal of applied physics
Jahrgang110
Ausgabenummer6
PublikationsstatusVeröffentlicht - 15 Sept. 2011
Extern publiziertJa

Abstract

Degradation of minority carrier lifetime under illumination occurs in boron-containing Czochralski silicon of both p- and n-type. In n-Si, the recombination centre responsible for degradation is found to be identical to the fast-stage centre (FRC) known for p-Si, where it is produced at a rate proportional to the squared hole concentration, p2. Holes in n-Si are the excess minority carriers-of a relatively low concentration; hence, the time scale of FRC generation is increased by several orders of magnitude when compared to p-Si. The degradation kinetics, which is non-linear, due to dependence of p on the current concentration of FRC, is well reproduced by simulations. The injection level dependence of the lifetime shows that FRC exists in 3 charge states (- 1, 0, 1) possessing 2 energy levels. Comparison of n-Si samples of various electron concentrations shows that FRC emerges by the reconstruction of a latent BsO2 complex of a substitutional boron and an oxygen dimer (while the major recombination centre in p-Si denoted SRC was previously found to emerge by reconstruction of B iO2 defect involving an interstitial boron atom). A model of the BsO2 reconfiguration into FRC through an intermediate state accounts for the rate constant dependence on p, which is reduced to a p2 proportionality, under certain conditions.

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Lifetime-degrading boron-oxygen centres in p-type and n-type compensated silicon. / Voronkov, V. V.; Falster, R.; Bothe, K. et al.
in: Journal of applied physics, Jahrgang 110, Nr. 6, 063515, 15.09.2011.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Voronkov VV, Falster R, Bothe K, Lim B, Schmidt J. Lifetime-degrading boron-oxygen centres in p-type and n-type compensated silicon. Journal of applied physics. 2011 Sep 15;110(6):063515. doi: 10.1063/1.3609069
Voronkov, V. V. ; Falster, R. ; Bothe, K. et al. / Lifetime-degrading boron-oxygen centres in p-type and n-type compensated silicon. in: Journal of applied physics. 2011 ; Jahrgang 110, Nr. 6.
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AU - Lim, B.

AU - Schmidt, J.

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