Lifetime degradation in multicrystalline silicon under illumination at elevated temperature: Indications for the involvement of hydrogen

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

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OriginalspracheEnglisch
Titel des SammelwerksSiliconPV 2018, the 8th International Conference on Crystalline Silicon Photovoltaics
Herausgeber/-innenRolf Brendel, Jef Poortmans, Arthur Weeber, Giso Hahn, Christophe Ballif, Stefan Glunz, Pierre-Jean Ribeyron
PublikationsstatusVeröffentlicht - 10 Aug. 2018
VeranstaltungSiliconPV 2018: The 8th International Conference on Crystalline Silicon Photovoltaics - Lausanne, Schweiz
Dauer: 19 März 201821 März 2018

Publikationsreihe

NameAIP Conference Proceedings
Band1999
ISSN (Print)0094-243X
ISSN (elektronisch)1551-7616

Abstract

We examine the lifetime degradation in multicrystalline silicon (mc-Si) under illumination at elevated temperature, an effect frequently denoted as 'LeTID' ('Light and elevated Temperature Induced Degradation'). Our lifetime analysis of belt-furnace-fired high-performance mc-Si wafers shows that LeTID is most pronounced on samples with Al2O3/SiNx-stack passivation. In contrast to that, the degradation on samples coated with Al2O3 single-layers is very small. We identify the presence of SiNx to be a key component to trigger the defect activation process. Our measurements suggest that hydrogen released during the high-temperature firing from the hydrogen-rich PECVD-deposited SiNx into the silicon bulk plays a major role in the defect activation process. Additionally, we find that the magnitude of lifetime degradation increases exponentially with increasing peak temperature during fast-firing. Comparing these results with recently published results from the literature, we conclude that hydrogen-metal complexes are possible candidates for the root cause of LeTID.

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Lifetime degradation in multicrystalline silicon under illumination at elevated temperature: Indications for the involvement of hydrogen. / Bredemeier, Dennis; Walter, Dominic C.; Schmidt, Jan.
SiliconPV 2018, the 8th International Conference on Crystalline Silicon Photovoltaics. Hrsg. / Rolf Brendel; Jef Poortmans; Arthur Weeber; Giso Hahn; Christophe Ballif; Stefan Glunz; Pierre-Jean Ribeyron. 2018. 130001 (AIP Conference Proceedings; Band 1999).

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Bredemeier, D, Walter, DC & Schmidt, J 2018, Lifetime degradation in multicrystalline silicon under illumination at elevated temperature: Indications for the involvement of hydrogen. in R Brendel, J Poortmans, A Weeber, G Hahn, C Ballif, S Glunz & P-J Ribeyron (Hrsg.), SiliconPV 2018, the 8th International Conference on Crystalline Silicon Photovoltaics., 130001, AIP Conference Proceedings, Bd. 1999, SiliconPV 2018: The 8th International Conference on Crystalline Silicon Photovoltaics, Lausanne, Schweiz, 19 März 2018. https://doi.org/10.1063/1.5049320
Bredemeier, D., Walter, D. C., & Schmidt, J. (2018). Lifetime degradation in multicrystalline silicon under illumination at elevated temperature: Indications for the involvement of hydrogen. In R. Brendel, J. Poortmans, A. Weeber, G. Hahn, C. Ballif, S. Glunz, & P.-J. Ribeyron (Hrsg.), SiliconPV 2018, the 8th International Conference on Crystalline Silicon Photovoltaics Artikel 130001 (AIP Conference Proceedings; Band 1999). https://doi.org/10.1063/1.5049320
Bredemeier D, Walter DC, Schmidt J. Lifetime degradation in multicrystalline silicon under illumination at elevated temperature: Indications for the involvement of hydrogen. in Brendel R, Poortmans J, Weeber A, Hahn G, Ballif C, Glunz S, Ribeyron PJ, Hrsg., SiliconPV 2018, the 8th International Conference on Crystalline Silicon Photovoltaics. 2018. 130001. (AIP Conference Proceedings). doi: 10.1063/1.5049320
Bredemeier, Dennis ; Walter, Dominic C. ; Schmidt, Jan. / Lifetime degradation in multicrystalline silicon under illumination at elevated temperature : Indications for the involvement of hydrogen. SiliconPV 2018, the 8th International Conference on Crystalline Silicon Photovoltaics. Hrsg. / Rolf Brendel ; Jef Poortmans ; Arthur Weeber ; Giso Hahn ; Christophe Ballif ; Stefan Glunz ; Pierre-Jean Ribeyron. 2018. (AIP Conference Proceedings).
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N2 - We examine the lifetime degradation in multicrystalline silicon (mc-Si) under illumination at elevated temperature, an effect frequently denoted as 'LeTID' ('Light and elevated Temperature Induced Degradation'). Our lifetime analysis of belt-furnace-fired high-performance mc-Si wafers shows that LeTID is most pronounced on samples with Al2O3/SiNx-stack passivation. In contrast to that, the degradation on samples coated with Al2O3 single-layers is very small. We identify the presence of SiNx to be a key component to trigger the defect activation process. Our measurements suggest that hydrogen released during the high-temperature firing from the hydrogen-rich PECVD-deposited SiNx into the silicon bulk plays a major role in the defect activation process. Additionally, we find that the magnitude of lifetime degradation increases exponentially with increasing peak temperature during fast-firing. Comparing these results with recently published results from the literature, we conclude that hydrogen-metal complexes are possible candidates for the root cause of LeTID.

AB - We examine the lifetime degradation in multicrystalline silicon (mc-Si) under illumination at elevated temperature, an effect frequently denoted as 'LeTID' ('Light and elevated Temperature Induced Degradation'). Our lifetime analysis of belt-furnace-fired high-performance mc-Si wafers shows that LeTID is most pronounced on samples with Al2O3/SiNx-stack passivation. In contrast to that, the degradation on samples coated with Al2O3 single-layers is very small. We identify the presence of SiNx to be a key component to trigger the defect activation process. Our measurements suggest that hydrogen released during the high-temperature firing from the hydrogen-rich PECVD-deposited SiNx into the silicon bulk plays a major role in the defect activation process. Additionally, we find that the magnitude of lifetime degradation increases exponentially with increasing peak temperature during fast-firing. Comparing these results with recently published results from the literature, we conclude that hydrogen-metal complexes are possible candidates for the root cause of LeTID.

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