Laboratory rotational spectroscopy of cyano substituted polycyclic aromatic hydrocarbons

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autorschaft

  • Don McNaughton
  • Michaela K. Jahn
  • Michael J. Travers
  • Dennis Wachsmuth
  • Peter D. Godfrey
  • Jens Uwe Grabow

Externe Organisationen

  • Monash University
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)5268-5273
Seitenumfang6
FachzeitschriftMonthly Notices of the Royal Astronomical Society
Jahrgang476
Ausgabenummer4
Frühes Online-Datum3 März 2018
PublikationsstatusVeröffentlicht - Juni 2018

Abstract

The rotational spectra of the four cyano substituted polycyclic aromatic hydrocarbon (PAH) molecules 1-cyanonaphthalene, 2-cyanonaphthalene, 9-cyanoanthracene, and 9- cyanophenanthrene have been recorded in molecular expansions using a Stark-modulated millimetre-wave spectrometer and a Fourier transform microwave spectrometer in the centimetre-wave region. The spectra have been assigned and fitted to provide molecular constants and quadrupole hyperfine constants of sufficient accuracy to enable complete hyperfine structure line predictions for interstellar searches. The data may provide a route into detection of small PAHs in the interstellar medium.

ASJC Scopus Sachgebiete

Zitieren

Laboratory rotational spectroscopy of cyano substituted polycyclic aromatic hydrocarbons. / McNaughton, Don; Jahn, Michaela K.; Travers, Michael J. et al.
in: Monthly Notices of the Royal Astronomical Society, Jahrgang 476, Nr. 4, 06.2018, S. 5268-5273.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

McNaughton, D, Jahn, MK, Travers, MJ, Wachsmuth, D, Godfrey, PD & Grabow, JU 2018, 'Laboratory rotational spectroscopy of cyano substituted polycyclic aromatic hydrocarbons', Monthly Notices of the Royal Astronomical Society, Jg. 476, Nr. 4, S. 5268-5273. https://doi.org/10.1093/MNRAS/STY557
McNaughton, D., Jahn, M. K., Travers, M. J., Wachsmuth, D., Godfrey, P. D., & Grabow, J. U. (2018). Laboratory rotational spectroscopy of cyano substituted polycyclic aromatic hydrocarbons. Monthly Notices of the Royal Astronomical Society, 476(4), 5268-5273. https://doi.org/10.1093/MNRAS/STY557
McNaughton D, Jahn MK, Travers MJ, Wachsmuth D, Godfrey PD, Grabow JU. Laboratory rotational spectroscopy of cyano substituted polycyclic aromatic hydrocarbons. Monthly Notices of the Royal Astronomical Society. 2018 Jun;476(4):5268-5273. Epub 2018 Mär 3. doi: 10.1093/MNRAS/STY557
McNaughton, Don ; Jahn, Michaela K. ; Travers, Michael J. et al. / Laboratory rotational spectroscopy of cyano substituted polycyclic aromatic hydrocarbons. in: Monthly Notices of the Royal Astronomical Society. 2018 ; Jahrgang 476, Nr. 4. S. 5268-5273.
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AU - Jahn, Michaela K.

AU - Travers, Michael J.

AU - Wachsmuth, Dennis

AU - Godfrey, Peter D.

AU - Grabow, Jens Uwe

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N2 - The rotational spectra of the four cyano substituted polycyclic aromatic hydrocarbon (PAH) molecules 1-cyanonaphthalene, 2-cyanonaphthalene, 9-cyanoanthracene, and 9- cyanophenanthrene have been recorded in molecular expansions using a Stark-modulated millimetre-wave spectrometer and a Fourier transform microwave spectrometer in the centimetre-wave region. The spectra have been assigned and fitted to provide molecular constants and quadrupole hyperfine constants of sufficient accuracy to enable complete hyperfine structure line predictions for interstellar searches. The data may provide a route into detection of small PAHs in the interstellar medium.

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