Iodine(III)-initiated bromoacetoxylation of olefins

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  • Technische Universität Clausthal
  • Jahangirnagar University
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OriginalspracheEnglisch
Seiten (von - bis)195-197
Seitenumfang3
FachzeitschriftSynlett
Ausgabenummer2
PublikationsstatusVeröffentlicht - Feb. 1998
Extern publiziertJa

Abstract

A new and mild method for the bromoacetoxylation of olefins is presented, which is initiated by iodine(III). α-Acetoxy bromides 6-11 are generated from olefins 5 in the presence of tetraethylammonium bromide (1) and (diacetoxyiodo)benzene (2). The 1,2-addition to carbohydrate-derived enol ethers results in 2-deoxy-2-bromo-pyranosyl acetates which are versatile glycosyl donors for the synthesis of 2′-deoxy-2′-bromo glycosides 16.

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Iodine(III)-initiated bromoacetoxylation of olefins. / Hashem, Md Abul; Jung, Alexander; Ries, Monika et al.
in: Synlett, Nr. 2, 02.1998, S. 195-197.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Hashem MA, Jung A, Ries M, Kirschning A. Iodine(III)-initiated bromoacetoxylation of olefins. Synlett. 1998 Feb;(2):195-197. doi: 10.1055/s-1998-1596
Hashem, Md Abul ; Jung, Alexander ; Ries, Monika et al. / Iodine(III)-initiated bromoacetoxylation of olefins. in: Synlett. 1998 ; Nr. 2. S. 195-197.
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