TY - JOUR

T1 - Investigation on elemental and isotopic fractionation during 196 nm femtosecond laser ablation multiple collector inductively coupled plasma mass spectrometry

AU - Horn, Ingo

AU - von Blanckenburg, Friedhelm

N1 - Funding Information: We acknowledge the support for this study by the DFG, Volkswagenstiftung and New Wave Research. S. Gruhl is thanked for help on the SEM and W. Hurkuck, B. Aichinger and O. Dietrich are thanked for technical support.

PY - 2007/4

Y1 - 2007/4

N2 - Despite the large number of successful applications of laser ablation, elemental and isotopic fractionation coupled to inductively coupled plasma mass spectrometry (ICP-MS) remain as the main limitations for many applications of this technique in the fields of analytical chemistry and Earth Sciences. A substantial effort has been made to control such fractionations, which are well-established features of nanosecond laser ablation systems. Technological advancements made over the past decade now allow the ablation of solids by femtosecond laser pulses in the deep ultraviolet (UV) region at wavelengths less than 200 nm. Here the use of femtosecond laser ablation and its effects on elemental and isotopic fractionation is investigated. The Pb/U system is used to illustrate elemental fractionation and stable Fe isotopes are used to illustrate isotopic fractionation. No elemental fractionation is observed beyond the precision of the multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) measurements. Without a matrix match between standard and sample, elemental fractionation is absent even when using different laser ablation protocols for standardization and samples (spot versus raster). Furthermore, we found that laser ablation-induced isotope ratio drifts, commonly observed during nanosecond laser ablation, are undetectable during ultraviolet femtosecond laser ablation. So far the precision obtained for Fe isotope ratio determinations is 0.1‰ (2 standard deviation) for the 56Fe/54Fe ratio. This is close to that obtainable by solution multiple-collector inductively coupled plasma mass spectrometry. The accuracy of the results appears to be independent of the matrix used for standardization. The resulting smaller particle sizes reduce fractionation processes. Femtosecond laser ablation carries the potential to solve some of the difficulties encountered during the two prior decades since the introduction of laser ablation.

AB - Despite the large number of successful applications of laser ablation, elemental and isotopic fractionation coupled to inductively coupled plasma mass spectrometry (ICP-MS) remain as the main limitations for many applications of this technique in the fields of analytical chemistry and Earth Sciences. A substantial effort has been made to control such fractionations, which are well-established features of nanosecond laser ablation systems. Technological advancements made over the past decade now allow the ablation of solids by femtosecond laser pulses in the deep ultraviolet (UV) region at wavelengths less than 200 nm. Here the use of femtosecond laser ablation and its effects on elemental and isotopic fractionation is investigated. The Pb/U system is used to illustrate elemental fractionation and stable Fe isotopes are used to illustrate isotopic fractionation. No elemental fractionation is observed beyond the precision of the multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) measurements. Without a matrix match between standard and sample, elemental fractionation is absent even when using different laser ablation protocols for standardization and samples (spot versus raster). Furthermore, we found that laser ablation-induced isotope ratio drifts, commonly observed during nanosecond laser ablation, are undetectable during ultraviolet femtosecond laser ablation. So far the precision obtained for Fe isotope ratio determinations is 0.1‰ (2 standard deviation) for the 56Fe/54Fe ratio. This is close to that obtainable by solution multiple-collector inductively coupled plasma mass spectrometry. The accuracy of the results appears to be independent of the matrix used for standardization. The resulting smaller particle sizes reduce fractionation processes. Femtosecond laser ablation carries the potential to solve some of the difficulties encountered during the two prior decades since the introduction of laser ablation.

KW - Elemental fractionation

KW - Fe isotopes

KW - Femtosecond laser ablation

KW - Geochronology

KW - Laser induced isotopic fractionation

UR - http://www.scopus.com/inward/record.url?scp=34249038090&partnerID=8YFLogxK

U2 - 10.1016/j.sab.2007.03.034

DO - 10.1016/j.sab.2007.03.034

M3 - Article

AN - SCOPUS:34249038090

VL - 62

SP - 410

EP - 422

JO - Spectrochimica Acta - Part B Atomic Spectroscopy

JF - Spectrochimica Acta - Part B Atomic Spectroscopy

SN - 0584-8547

IS - 4

ER -