Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 129-132 |
| Seitenumfang | 4 |
| Fachzeitschrift | Hyperfine Interactions |
| Jahrgang | 185 |
| Ausgabenummer | 1-3 |
| Publikationsstatus | Veröffentlicht - Juli 2008 |
| Extern publiziert | Ja |
Abstract
Systematic 119mSn-Mössbauer spectroscopy studies of three different types of five and six coordinated molybdenum and tungsten stannylidyne complexes are presented. The measured isomer shifts (IS) range from 2.38 to 2.50 mm/s and the quadrupole splittings (QS) from 1.8 to 2.8 mm/s. The values are dependent on the metal centre, the ligand sphere and the charge of the complexes. The influence of the neighbouring metal atoms (Mo, W) and their coordination sphere on the electron density at the tin atom is observed and will be discussed.
ASJC Scopus Sachgebiete
- Physik und Astronomie (insg.)
- Atom- und Molekularphysik sowie Optik
- Physik und Astronomie (insg.)
- Kern- und Hochenergiephysik
- Physik und Astronomie (insg.)
- Physik der kondensierten Materie
- Chemie (insg.)
- Physikalische und Theoretische Chemie
Zitieren
- Standard
- Harvard
- Apa
- Vancouver
- BibTex
- RIS
in: Hyperfine Interactions, Jahrgang 185, Nr. 1-3, 07.2008, S. 129-132.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Investigation of Mo- and W-stannylidyne complexes by Mössbauer spectroscopy
AU - Rohde, H.
AU - Menzel, M.
AU - Renz, F.
AU - Filippou, A. C.
PY - 2008/7
Y1 - 2008/7
N2 - Systematic 119mSn-Mössbauer spectroscopy studies of three different types of five and six coordinated molybdenum and tungsten stannylidyne complexes are presented. The measured isomer shifts (IS) range from 2.38 to 2.50 mm/s and the quadrupole splittings (QS) from 1.8 to 2.8 mm/s. The values are dependent on the metal centre, the ligand sphere and the charge of the complexes. The influence of the neighbouring metal atoms (Mo, W) and their coordination sphere on the electron density at the tin atom is observed and will be discussed.
AB - Systematic 119mSn-Mössbauer spectroscopy studies of three different types of five and six coordinated molybdenum and tungsten stannylidyne complexes are presented. The measured isomer shifts (IS) range from 2.38 to 2.50 mm/s and the quadrupole splittings (QS) from 1.8 to 2.8 mm/s. The values are dependent on the metal centre, the ligand sphere and the charge of the complexes. The influence of the neighbouring metal atoms (Mo, W) and their coordination sphere on the electron density at the tin atom is observed and will be discussed.
KW - Sn-Mössbauer spectroscopy
KW - Molybdenum
KW - Phosphane complexes
KW - Stannylidyne complexes
KW - Tungsten
UR - http://www.scopus.com/inward/record.url?scp=67650422254&partnerID=8YFLogxK
U2 - 10.1007/s10751-008-9821-7
DO - 10.1007/s10751-008-9821-7
M3 - Article
AN - SCOPUS:67650422254
VL - 185
SP - 129
EP - 132
JO - Hyperfine Interactions
JF - Hyperfine Interactions
SN - 0304-3843
IS - 1-3
ER -