Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 8367-8369 |
| Seitenumfang | 3 |
| Fachzeitschrift | Angewandte Chemie - International Edition |
| Jahrgang | 49 |
| Ausgabenummer | 45 |
| Publikationsstatus | Veröffentlicht - 2 Nov. 2010 |
| Extern publiziert | Ja |
Abstract
Picking sides: Asymmetric protonation of the titled compounds poses a most significant challenge and has been addressed by taking advantage of internal protonation and subsequent hemiacetal formation to avoid epimerization (see scheme). The substrates employed in these transformations can be easily accessed through a sequence of vinylogous aldol reactions with subsequent conjugate reductions.
ASJC Scopus Sachgebiete
- Chemische Verfahrenstechnik (insg.)
- Katalyse
- Chemie (insg.)
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in: Angewandte Chemie - International Edition, Jahrgang 49, Nr. 45, 02.11.2010, S. 8367-8369.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Intramolecular stereoselective protonation of aldehyde-derived enolates
AU - Kena-diba, Anastasie
AU - Noll, Claudia
AU - Richter, Michael
AU - Gieseler, Marc Timo
AU - Kalesse, Markus
PY - 2010/11/2
Y1 - 2010/11/2
N2 - Picking sides: Asymmetric protonation of the titled compounds poses a most significant challenge and has been addressed by taking advantage of internal protonation and subsequent hemiacetal formation to avoid epimerization (see scheme). The substrates employed in these transformations can be easily accessed through a sequence of vinylogous aldol reactions with subsequent conjugate reductions.
AB - Picking sides: Asymmetric protonation of the titled compounds poses a most significant challenge and has been addressed by taking advantage of internal protonation and subsequent hemiacetal formation to avoid epimerization (see scheme). The substrates employed in these transformations can be easily accessed through a sequence of vinylogous aldol reactions with subsequent conjugate reductions.
KW - Asymmetric catalysis
KW - Natural products
KW - Organocatalysis
KW - Protonation
KW - Reduction
UR - http://www.scopus.com/inward/record.url?scp=78149426244&partnerID=8YFLogxK
U2 - 10.1002/anie.201004619
DO - 10.1002/anie.201004619
M3 - Article
C2 - 20878962
AN - SCOPUS:78149426244
VL - 49
SP - 8367
EP - 8369
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 45
ER -