In-Plane Phonon Density of States of Li-Graphite Intercalation Compounds

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • A. Schirmer
  • J. E. Fischer
  • P. Heitjans
  • H. J. Kim
  • A. Magerl
  • D. Varnin
  • H. Zabel

Externe Organisationen

  • University of Pennsylvania
  • Ruhr-Universität Bochum
  • Institut Laue-Langevin
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Details

OriginalspracheEnglisch
Seiten (von - bis)299-305
Seitenumfang7
FachzeitschriftMolecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Jahrgang244
Ausgabenummer1
PublikationsstatusVeröffentlicht - Apr. 1994

Abstract

The inplane phonon densities of states of Li-graphite intercalation compounds of stage-1 and stage-2 are obtained from neutron time-of-flight spectra. For the stage-2 the ordered compound LiC12 which has the same inplane structure as the stage-1 compound LiCß as well as the dilute compound LiC16 which only reveals short range order were studied. The temperature in the measurements was extended above expected phase transitions for both stages and the density of states is analysed in terms of the effective temperatures T for the inplane vibrational energies. T\\ shows characteristic changes at the thermodynamic temperatures of the phase tansitions. Comparison of the T|| values shows similar inplane dynamics of all Li-compounds at the highest temperatures.

ASJC Scopus Sachgebiete

Zitieren

In-Plane Phonon Density of States of Li-Graphite Intercalation Compounds. / Schirmer, A.; Fischer, J. E.; Heitjans, P. et al.
in: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Jahrgang 244, Nr. 1, 04.1994, S. 299-305.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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abstract = "The inplane phonon densities of states of Li-graphite intercalation compounds of stage-1 and stage-2 are obtained from neutron time-of-flight spectra. For the stage-2 the ordered compound LiC12 which has the same inplane structure as the stage-1 compound LiC{\ss} as well as the dilute compound LiC16 which only reveals short range order were studied. The temperature in the measurements was extended above expected phase transitions for both stages and the density of states is analysed in terms of the effective temperatures T for the inplane vibrational energies. T\\ shows characteristic changes at the thermodynamic temperatures of the phase tansitions. Comparison of the T|| values shows similar inplane dynamics of all Li-compounds at the highest temperatures.",
author = "A. Schirmer and Fischer, {J. E.} and P. Heitjans and Kim, {H. J.} and A. Magerl and D. Varnin and H. Zabel",
note = "Funding Information: The work at the Univ. l.Jnnovcr an' the Univ. of Pennsylvania has been supported by the Bundesministerium fiir Forschung urid Technologie (HEJHAN) and the Department of Energy (DE-FC02-86ER45254), respectively.",
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TY - JOUR

T1 - In-Plane Phonon Density of States of Li-Graphite Intercalation Compounds

AU - Schirmer, A.

AU - Fischer, J. E.

AU - Heitjans, P.

AU - Kim, H. J.

AU - Magerl, A.

AU - Varnin, D.

AU - Zabel, H.

N1 - Funding Information: The work at the Univ. l.Jnnovcr an' the Univ. of Pennsylvania has been supported by the Bundesministerium fiir Forschung urid Technologie (HEJHAN) and the Department of Energy (DE-FC02-86ER45254), respectively.

PY - 1994/4

Y1 - 1994/4

N2 - The inplane phonon densities of states of Li-graphite intercalation compounds of stage-1 and stage-2 are obtained from neutron time-of-flight spectra. For the stage-2 the ordered compound LiC12 which has the same inplane structure as the stage-1 compound LiCß as well as the dilute compound LiC16 which only reveals short range order were studied. The temperature in the measurements was extended above expected phase transitions for both stages and the density of states is analysed in terms of the effective temperatures T for the inplane vibrational energies. T\\ shows characteristic changes at the thermodynamic temperatures of the phase tansitions. Comparison of the T|| values shows similar inplane dynamics of all Li-compounds at the highest temperatures.

AB - The inplane phonon densities of states of Li-graphite intercalation compounds of stage-1 and stage-2 are obtained from neutron time-of-flight spectra. For the stage-2 the ordered compound LiC12 which has the same inplane structure as the stage-1 compound LiCß as well as the dilute compound LiC16 which only reveals short range order were studied. The temperature in the measurements was extended above expected phase transitions for both stages and the density of states is analysed in terms of the effective temperatures T for the inplane vibrational energies. T\\ shows characteristic changes at the thermodynamic temperatures of the phase tansitions. Comparison of the T|| values shows similar inplane dynamics of all Li-compounds at the highest temperatures.

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U2 - 10.1080/10587259408050121

DO - 10.1080/10587259408050121

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VL - 244

SP - 299

EP - 305

JO - Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals

SN - 1058-725X

IS - 1

ER -

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