Indium mediated allylation of glyoxylate oxime ethers, esters and cyanoformates

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

Externe Organisationen

  • University of Bristol
  • GlaxoSmithKline GmbH and Co. KG (GSK)
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Details

OriginalspracheEnglisch
Seiten (von - bis)1921-1933
Seitenumfang13
FachzeitschriftOrganic and Biomolecular Chemistry
Jahrgang2
Ausgabenummer13
PublikationsstatusVeröffentlicht - 7 Juli 2004
Extern publiziertJa

Abstract

An indium mediated procedure has been developed for the allylation of activated O-functionalised oximes and nitriles as exemplified by a variety of glyoxylate derivatives. This method gives the corresponding free (or protected) amine in a one pot-process. The method is regiospecific and is carried out under remarkably mild conditions so that even oxime esters can be subjected to the typical reaction conditions.

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Indium mediated allylation of glyoxylate oxime ethers, esters and cyanoformates. / Ritson, Dougal J.; Cox, Russell J.; Berge, John.
in: Organic and Biomolecular Chemistry, Jahrgang 2, Nr. 13, 07.07.2004, S. 1921-1933.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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