High-spin wheel of a heptanuclear mixed-valent FeII,III complex

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autorschaft

  • Hiroki Oshio
  • Norihisa Hoshino
  • Tasuku Ito
  • Motohiro Nakano
  • Franz Renz
  • Philipp Gütlich

Externe Organisationen

  • University of Tsukuba
  • Tohoku University
  • Osaka University
  • Johannes Gutenberg-Universität Mainz
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)223-225
Seitenumfang3
FachzeitschriftAngewandte Chemie - International Edition
Jahrgang42
Ausgabenummer2
PublikationsstatusVeröffentlicht - 13 Jan. 2003
Extern publiziertJa

Abstract

Wheels with high spins: The reaction of a tridentate Schiff base ligand with iron (II) chloride, and subsequent oxidation with [(tBu4N) MnO4] yielded a heptanuclear mixed-valent iron wheel (see picture) with a spin ground state of S = 29/2. Cornering the 13th vertex: The first 13-vertex carborane (see picture, B: brown, C: gray, H: white) has been prepared by a methodology that can in principle be applied repeatedly, leading to 14-, 15-, 16-, ... vertex carboranes in the future. The 13-vertex species has a henicosahedral geometry, not the docosahedral one expected, but the two forms are found to be very close in energy by DFT calculations.

ASJC Scopus Sachgebiete

Zitieren

High-spin wheel of a heptanuclear mixed-valent FeII,III complex. / Oshio, Hiroki; Hoshino, Norihisa; Ito, Tasuku et al.
in: Angewandte Chemie - International Edition, Jahrgang 42, Nr. 2, 13.01.2003, S. 223-225.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Oshio, H, Hoshino, N, Ito, T, Nakano, M, Renz, F & Gütlich, P 2003, 'High-spin wheel of a heptanuclear mixed-valent FeII,III complex', Angewandte Chemie - International Edition, Jg. 42, Nr. 2, S. 223-225. https://doi.org/10.1002/anie.200390084
Oshio, H., Hoshino, N., Ito, T., Nakano, M., Renz, F., & Gütlich, P. (2003). High-spin wheel of a heptanuclear mixed-valent FeII,III complex. Angewandte Chemie - International Edition, 42(2), 223-225. https://doi.org/10.1002/anie.200390084
Oshio H, Hoshino N, Ito T, Nakano M, Renz F, Gütlich P. High-spin wheel of a heptanuclear mixed-valent FeII,III complex. Angewandte Chemie - International Edition. 2003 Jan 13;42(2):223-225. doi: 10.1002/anie.200390084
Oshio, Hiroki ; Hoshino, Norihisa ; Ito, Tasuku et al. / High-spin wheel of a heptanuclear mixed-valent FeII,III complex. in: Angewandte Chemie - International Edition. 2003 ; Jahrgang 42, Nr. 2. S. 223-225.
Download
@article{50ebe1cad0bc4d91923710a407f34ae3,
title = "High-spin wheel of a heptanuclear mixed-valent FeII,III complex",
abstract = "Wheels with high spins: The reaction of a tridentate Schiff base ligand with iron (II) chloride, and subsequent oxidation with [(tBu4N) MnO4] yielded a heptanuclear mixed-valent iron wheel (see picture) with a spin ground state of S = 29/2. Cornering the 13th vertex: The first 13-vertex carborane (see picture, B: brown, C: gray, H: white) has been prepared by a methodology that can in principle be applied repeatedly, leading to 14-, 15-, 16-, ... vertex carboranes in the future. The 13-vertex species has a henicosahedral geometry, not the docosahedral one expected, but the two forms are found to be very close in energy by DFT calculations.",
keywords = "Cluster compounds, High-spin molecules, Iron, Magnetic properties, Mixed-valent compounds",
author = "Hiroki Oshio and Norihisa Hoshino and Tasuku Ito and Motohiro Nakano and Franz Renz and Philipp G{\"u}tlich",
year = "2003",
month = jan,
day = "13",
doi = "10.1002/anie.200390084",
language = "English",
volume = "42",
pages = "223--225",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "2",

}

Download

TY - JOUR

T1 - High-spin wheel of a heptanuclear mixed-valent FeII,III complex

AU - Oshio, Hiroki

AU - Hoshino, Norihisa

AU - Ito, Tasuku

AU - Nakano, Motohiro

AU - Renz, Franz

AU - Gütlich, Philipp

PY - 2003/1/13

Y1 - 2003/1/13

N2 - Wheels with high spins: The reaction of a tridentate Schiff base ligand with iron (II) chloride, and subsequent oxidation with [(tBu4N) MnO4] yielded a heptanuclear mixed-valent iron wheel (see picture) with a spin ground state of S = 29/2. Cornering the 13th vertex: The first 13-vertex carborane (see picture, B: brown, C: gray, H: white) has been prepared by a methodology that can in principle be applied repeatedly, leading to 14-, 15-, 16-, ... vertex carboranes in the future. The 13-vertex species has a henicosahedral geometry, not the docosahedral one expected, but the two forms are found to be very close in energy by DFT calculations.

AB - Wheels with high spins: The reaction of a tridentate Schiff base ligand with iron (II) chloride, and subsequent oxidation with [(tBu4N) MnO4] yielded a heptanuclear mixed-valent iron wheel (see picture) with a spin ground state of S = 29/2. Cornering the 13th vertex: The first 13-vertex carborane (see picture, B: brown, C: gray, H: white) has been prepared by a methodology that can in principle be applied repeatedly, leading to 14-, 15-, 16-, ... vertex carboranes in the future. The 13-vertex species has a henicosahedral geometry, not the docosahedral one expected, but the two forms are found to be very close in energy by DFT calculations.

KW - Cluster compounds

KW - High-spin molecules

KW - Iron

KW - Magnetic properties

KW - Mixed-valent compounds

UR - http://www.scopus.com/inward/record.url?scp=0037434151&partnerID=8YFLogxK

U2 - 10.1002/anie.200390084

DO - 10.1002/anie.200390084

M3 - Article

AN - SCOPUS:0037434151

VL - 42

SP - 223

EP - 225

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 2

ER -