High-quality exfoliated crystalline silicon foils for solar cell applications

Publikation: Beitrag in FachzeitschriftKonferenzaufsatz in FachzeitschriftForschungPeer-Review

Autoren

  • Raphael Niepelt
  • Alwina Knorr
  • Verena Steckenreiter
  • Sarah Kajari-Schoder
  • Rolf Brendel
  • J. Hensen

Organisationseinheiten

Externe Organisationen

  • Institut für Solarenergieforschung GmbH (ISFH)
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Details

OriginalspracheEnglisch
Seiten (von - bis)570-577
Seitenumfang8
FachzeitschriftEnergy Procedia
Jahrgang55
PublikationsstatusVeröffentlicht - 2014
Veranstaltung4th International Conference on Crystalline Silicon Photovoltaics, SiliconPV 2014 - Hertogenbosch, Niederlande
Dauer: 25 März 201427 März 2014

Abstract

Kerfless wafering techniques offer a significant cost saving potential via the reduction of silicon consumption. In this paper, we examine thin single crystalline Si foils that were fabricated by a novel kerfless thermo-mechanical exfoliation method utilizing evaporated Al with regard to their suitability for solar cell applications. The foils are 50-80 μm thick and smooth to visual inspection across the almost entire surface. We measure the effective minority carrier lifetimes of the foils and the remaining parent substrates by quasi-steady-state photoconductance (QSSPC) and spatially resolved by dynamically calibrated steady state infrared carrier lifetime mapping (dynILM). We find lifetimes of above 120 μs for kerfless exfoliated 0.5 Ωcm p-type float-zone (FZ) Si layers. With an additional etching step after exfoliation, we obtain effective lifetimes of above 200 μs. The measurements reveal that there is no critical lifetime degradation due to exfoliation-induced surface features and thus the exfoliated layers are well-suited for high-quality solar cells.

ASJC Scopus Sachgebiete

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High-quality exfoliated crystalline silicon foils for solar cell applications. / Niepelt, Raphael; Knorr, Alwina; Steckenreiter, Verena et al.
in: Energy Procedia, Jahrgang 55, 2014, S. 570-577.

Publikation: Beitrag in FachzeitschriftKonferenzaufsatz in FachzeitschriftForschungPeer-Review

Niepelt, R, Knorr, A, Steckenreiter, V, Kajari-Schoder, S, Brendel, R & Hensen, J 2014, 'High-quality exfoliated crystalline silicon foils for solar cell applications', Energy Procedia, Jg. 55, S. 570-577. https://doi.org/10.1016/j.egypro.2014.08.028
Niepelt, R., Knorr, A., Steckenreiter, V., Kajari-Schoder, S., Brendel, R., & Hensen, J. (2014). High-quality exfoliated crystalline silicon foils for solar cell applications. Energy Procedia, 55, 570-577. https://doi.org/10.1016/j.egypro.2014.08.028
Niepelt R, Knorr A, Steckenreiter V, Kajari-Schoder S, Brendel R, Hensen J. High-quality exfoliated crystalline silicon foils for solar cell applications. Energy Procedia. 2014;55:570-577. doi: 10.1016/j.egypro.2014.08.028
Niepelt, Raphael ; Knorr, Alwina ; Steckenreiter, Verena et al. / High-quality exfoliated crystalline silicon foils for solar cell applications. in: Energy Procedia. 2014 ; Jahrgang 55. S. 570-577.
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AU - Niepelt, Raphael

AU - Knorr, Alwina

AU - Steckenreiter, Verena

AU - Kajari-Schoder, Sarah

AU - Brendel, Rolf

AU - Hensen, J.

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AB - Kerfless wafering techniques offer a significant cost saving potential via the reduction of silicon consumption. In this paper, we examine thin single crystalline Si foils that were fabricated by a novel kerfless thermo-mechanical exfoliation method utilizing evaporated Al with regard to their suitability for solar cell applications. The foils are 50-80 μm thick and smooth to visual inspection across the almost entire surface. We measure the effective minority carrier lifetimes of the foils and the remaining parent substrates by quasi-steady-state photoconductance (QSSPC) and spatially resolved by dynamically calibrated steady state infrared carrier lifetime mapping (dynILM). We find lifetimes of above 120 μs for kerfless exfoliated 0.5 Ωcm p-type float-zone (FZ) Si layers. With an additional etching step after exfoliation, we obtain effective lifetimes of above 200 μs. The measurements reveal that there is no critical lifetime degradation due to exfoliation-induced surface features and thus the exfoliated layers are well-suited for high-quality solar cells.

KW - Carrier lifetime

KW - Exfoliation

KW - Kerf-free

KW - Layer transfer

KW - Photovoltaic

KW - Spalling

KW - Wafering

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