Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 2692-2696 |
| Seitenumfang | 5 |
| Fachzeitschrift | Synlett |
| Ausgabenummer | 17 |
| Publikationsstatus | Veröffentlicht - 1 Okt. 2008 |
Abstract
When an 2-isopropoxy-substituted benzylidene ligand of a Hoveyda-type Ru-metathesis complex is modified by an additional 4-diethylamino group and treated wit PTSA it yields a highly active precatalyst suitable for RCM, cross metathesis, and enyne metathesis. The important property of this ammonium tagged Ru-complex is associated with the possibility of its easy removal by a simple filtration protocol.
ASJC Scopus Sachgebiete
- Chemie (insg.)
- Organische Chemie
Zitieren
- Standard
- Harvard
- Apa
- Vancouver
- BibTex
- RIS
in: Synlett, Nr. 17, 01.10.2008, S. 2692-2696.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Highly active ammonium-tagged olefin-metathesis catalyst for simplified purification
AU - Kirschning, Andreas
AU - Gułajski, Lukasz
AU - Mennecke, Klaas
AU - Meyer, Axel
AU - Busch, Torsten
AU - Grela, Karol
PY - 2008/10/1
Y1 - 2008/10/1
N2 - When an 2-isopropoxy-substituted benzylidene ligand of a Hoveyda-type Ru-metathesis complex is modified by an additional 4-diethylamino group and treated wit PTSA it yields a highly active precatalyst suitable for RCM, cross metathesis, and enyne metathesis. The important property of this ammonium tagged Ru-complex is associated with the possibility of its easy removal by a simple filtration protocol.
AB - When an 2-isopropoxy-substituted benzylidene ligand of a Hoveyda-type Ru-metathesis complex is modified by an additional 4-diethylamino group and treated wit PTSA it yields a highly active precatalyst suitable for RCM, cross metathesis, and enyne metathesis. The important property of this ammonium tagged Ru-complex is associated with the possibility of its easy removal by a simple filtration protocol.
KW - Catalysis
KW - Olefin metathesis
KW - Ruthenium catalyst
KW - Tag
UR - http://www.scopus.com/inward/record.url?scp=55449115052&partnerID=8YFLogxK
U2 - 10.1055/s-0028-1083512
DO - 10.1055/s-0028-1083512
M3 - Article
AN - SCOPUS:55449115052
SP - 2692
EP - 2696
JO - Synlett
JF - Synlett
SN - 0936-5214
IS - 17
ER -