Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 2653-2655 |
| Seitenumfang | 3 |
| Fachzeitschrift | European Journal of Inorganic Chemistry |
| Ausgabenummer | 16 |
| Frühes Online-Datum | 24 Apr. 2012 |
| Publikationsstatus | Veröffentlicht - Juni 2012 |
Abstract
In this contribution, we report the first hard-X-ray-induced thermal hysteresis (HAXITH). The bistability in [Fe(phen) 2(SCN) 2] (phen = 1,10-phenanthroline) is proven by alternately heating and cooling the sample under permanent irradiation with hard X-rays. Within the hysteresis a serpentine-like switching effect is observed. HAXITH is a new tool to monitor cooperativity among the switching units. It exhibits a threshold similar to that observed with visible light excitations.
ASJC Scopus Sachgebiete
- Chemie (insg.)
- Anorganische Chemie
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in: European Journal of Inorganic Chemistry, Nr. 16, 06.2012, S. 2653-2655.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Hard-X-ray-Induced Thermal Hysteresis (HAXITH) in a Molecular Switchable Solid
AU - Renz, Franz
AU - Vankó, György
AU - Homenya, Patrick
AU - Saadat, Reza
AU - Németh, Zoltán
AU - Huotari, Simo
PY - 2012/6
Y1 - 2012/6
N2 - In this contribution, we report the first hard-X-ray-induced thermal hysteresis (HAXITH). The bistability in [Fe(phen) 2(SCN) 2] (phen = 1,10-phenanthroline) is proven by alternately heating and cooling the sample under permanent irradiation with hard X-rays. Within the hysteresis a serpentine-like switching effect is observed. HAXITH is a new tool to monitor cooperativity among the switching units. It exhibits a threshold similar to that observed with visible light excitations.
AB - In this contribution, we report the first hard-X-ray-induced thermal hysteresis (HAXITH). The bistability in [Fe(phen) 2(SCN) 2] (phen = 1,10-phenanthroline) is proven by alternately heating and cooling the sample under permanent irradiation with hard X-rays. Within the hysteresis a serpentine-like switching effect is observed. HAXITH is a new tool to monitor cooperativity among the switching units. It exhibits a threshold similar to that observed with visible light excitations.
KW - Iron
KW - Magnetic properties
KW - Molecular switching
KW - Spin crossover
KW - X-ray spectroscopy
UR - http://www.scopus.com/inward/record.url?scp=84861309117&partnerID=8YFLogxK
U2 - 10.1002/ejic.201200025
DO - 10.1002/ejic.201200025
M3 - Article
AN - SCOPUS:84861309117
SP - 2653
EP - 2655
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 16
ER -