Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 11698-11700 |
| Seitenumfang | 3 |
| Fachzeitschrift | Angewandte Chemie - International Edition |
| Jahrgang | 52 |
| Ausgabenummer | 45 |
| Publikationsstatus | Veröffentlicht - 4 Nov. 2013 |
Abstract
Optical activity can be positive or negative depending on whether the electric and magnetic dipole transition moments point into the same or opposite halves of a sphere centered on the molecule. A new technique takes a different route: Radiation emitted by molecules of opposite chirality associated with a loop of three dipole-allowed transitions between rotational states is exactly out of phase, thus providing a direct signal of molecular chirality.
ASJC Scopus Sachgebiete
- Chemische Verfahrenstechnik (insg.)
- Katalyse
- Chemie (insg.)
- Allgemeine Chemie
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in: Angewandte Chemie - International Edition, Jahrgang 52, Nr. 45, 04.11.2013, S. 11698-11700.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Fourier transform microwave spectroscopy
T2 - Handedness caught by rotational coherence
AU - Grabow, Jens Uwe
PY - 2013/11/4
Y1 - 2013/11/4
N2 - Optical activity can be positive or negative depending on whether the electric and magnetic dipole transition moments point into the same or opposite halves of a sphere centered on the molecule. A new technique takes a different route: Radiation emitted by molecules of opposite chirality associated with a loop of three dipole-allowed transitions between rotational states is exactly out of phase, thus providing a direct signal of molecular chirality.
AB - Optical activity can be positive or negative depending on whether the electric and magnetic dipole transition moments point into the same or opposite halves of a sphere centered on the molecule. A new technique takes a different route: Radiation emitted by molecules of opposite chirality associated with a loop of three dipole-allowed transitions between rotational states is exactly out of phase, thus providing a direct signal of molecular chirality.
KW - chirality
KW - enantiomers
KW - handedness
KW - microwave spectroscopy
KW - molecular rotation
UR - http://www.scopus.com/inward/record.url?scp=84886784564&partnerID=8YFLogxK
U2 - 10.1002/anie.201307159
DO - 10.1002/anie.201307159
M3 - Article
AN - SCOPUS:84886784564
VL - 52
SP - 11698
EP - 11700
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 45
ER -