Enantioselective synthesis of polyketide segments through vinylogous Mukaiyama aldol reactions

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OriginalspracheEnglisch
Seiten (von - bis)3485-3488
Seitenumfang4
FachzeitschriftTetrahedron letters
Jahrgang50
Ausgabenummer26
PublikationsstatusVeröffentlicht - 1 Juli 2009

Abstract

The synthesis of polyketide segments through the vinylogous Mukaiyama aldol reaction is reported. The use of chiral oxazaborolidines allows using terminal substituted ketene acetals and provides access to extended segments and two new chiral centers.

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Enantioselective synthesis of polyketide segments through vinylogous Mukaiyama aldol reactions. / Simsek, Serkan; Kalesse, Markus.
in: Tetrahedron letters, Jahrgang 50, Nr. 26, 01.07.2009, S. 3485-3488.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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title = "Enantioselective synthesis of polyketide segments through vinylogous Mukaiyama aldol reactions",
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keywords = "Enantioselective, Natural products, Oxazaborolidines, Polyketides, Vinylogous Mukaiyama aldol",
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AU - Kalesse, Markus

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KW - Enantioselective

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