Electronic structure of silver oxides investigated by AgL XANES spectroscopy

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autoren

  • Peter Behrens
  • Stefanie Aßmann
  • Uta Bilow
  • Christoph Linke
  • Martin Jansen

Externe Organisationen

  • Ludwig-Maximilians-Universität München (LMU)
  • Universität Konstanz
  • Max-Planck-Institut für Festkörperforschung
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)111-116
Seitenumfang6
FachzeitschriftZeitschrift fur Anorganische und Allgemeine Chemie
Jahrgang625
Ausgabenummer1
PublikationsstatusVeröffentlicht - Jan. 1999
Extern publiziertJa

Abstract

The chemistry of binary and multinary silver oxides spans from subvalent species (with a mean oxidation number for Ag smaller than + 1) to compounds with Ag in high oxidation states as + 2 and + 3. We have investigated a range of silver oxides, including the binary compounds Ag2O, AgO, Ag3O4 and Ag2O3 as well as subvalent ternary oxides, by AgL3 and AgL1 XANES spectroscopy. The different valence states of silver are clearly reflected in AgL3 and AgL1 XANES spectra. The method thus allows the determination of average oxidation numbers. In addition, the degree of electronic interaction (localized or delocalized electronic states) in silver-oxygen compounds can be estimated on the basis of AgL3 XANES spectra.

ASJC Scopus Sachgebiete

Zitieren

Electronic structure of silver oxides investigated by AgL XANES spectroscopy. / Behrens, Peter; Aßmann, Stefanie; Bilow, Uta et al.
in: Zeitschrift fur Anorganische und Allgemeine Chemie, Jahrgang 625, Nr. 1, 01.1999, S. 111-116.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Behrens P, Aßmann S, Bilow U, Linke C, Jansen M. Electronic structure of silver oxides investigated by AgL XANES spectroscopy. Zeitschrift fur Anorganische und Allgemeine Chemie. 1999 Jan;625(1):111-116. doi: 10.1002/(sici)1521-3749(199901)625:1<111::aid-zaac111>3.0.co;2-7
Behrens, Peter ; Aßmann, Stefanie ; Bilow, Uta et al. / Electronic structure of silver oxides investigated by AgL XANES spectroscopy. in: Zeitschrift fur Anorganische und Allgemeine Chemie. 1999 ; Jahrgang 625, Nr. 1. S. 111-116.
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AU - Aßmann, Stefanie

AU - Bilow, Uta

AU - Linke, Christoph

AU - Jansen, Martin

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N2 - The chemistry of binary and multinary silver oxides spans from subvalent species (with a mean oxidation number for Ag smaller than + 1) to compounds with Ag in high oxidation states as + 2 and + 3. We have investigated a range of silver oxides, including the binary compounds Ag2O, AgO, Ag3O4 and Ag2O3 as well as subvalent ternary oxides, by AgL3 and AgL1 XANES spectroscopy. The different valence states of silver are clearly reflected in AgL3 and AgL1 XANES spectra. The method thus allows the determination of average oxidation numbers. In addition, the degree of electronic interaction (localized or delocalized electronic states) in silver-oxygen compounds can be estimated on the basis of AgL3 XANES spectra.

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