Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 381-387 |
| Seitenumfang | 7 |
| Fachzeitschrift | Journal of Sensors and Sensor Systems |
| Jahrgang | 6 |
| Ausgabenummer | 2 |
| Publikationsstatus | Veröffentlicht - 14 Dez. 2017 |
Abstract
Gas chromatographs with electron capture detectors are widely used for the analysis of electron affine substances such as pesticides or chlorofluorocarbons. With detection limits in the low pptv range, electron capture detectors are the most sensitive detectors available for such compounds. Based on their operating principle, they require free electrons at atmospheric pressure, which are usually generated by a β- decay. However, the use of radioactive materials leads to regulatory restrictions regarding purchase, operation, and disposal. Here, we present a novel electron capture detector based on a non-radioactive electron source that shows similar detection limits compared to radioactive detectors but that is not subject to these limitations and offers further advantages such as adjustable electron densities and energies. In this work we show first experimental results using 1,1,2-trichloroethane and sevoflurane, and investigate the effect of several operating parameters on the analytical performance of this new non-radioactive electron capture detector (ECD).
ASJC Scopus Sachgebiete
- Physik und Astronomie (insg.)
- Instrumentierung
- Ingenieurwesen (insg.)
- Elektrotechnik und Elektronik
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in: Journal of Sensors and Sensor Systems, Jahrgang 6, Nr. 2, 14.12.2017, S. 381-387.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Electron capture detector based on a non-radioactive electron source
T2 - operating parameters vs. analytical performance
AU - Bunert, Erik
AU - Kirk, Ansgar T.
AU - Oermann, Jens
AU - Zimmermann, Stefan
N1 - Publisher Copyright: © Author(s) 2017. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2017/12/14
Y1 - 2017/12/14
N2 - Gas chromatographs with electron capture detectors are widely used for the analysis of electron affine substances such as pesticides or chlorofluorocarbons. With detection limits in the low pptv range, electron capture detectors are the most sensitive detectors available for such compounds. Based on their operating principle, they require free electrons at atmospheric pressure, which are usually generated by a β- decay. However, the use of radioactive materials leads to regulatory restrictions regarding purchase, operation, and disposal. Here, we present a novel electron capture detector based on a non-radioactive electron source that shows similar detection limits compared to radioactive detectors but that is not subject to these limitations and offers further advantages such as adjustable electron densities and energies. In this work we show first experimental results using 1,1,2-trichloroethane and sevoflurane, and investigate the effect of several operating parameters on the analytical performance of this new non-radioactive electron capture detector (ECD).
AB - Gas chromatographs with electron capture detectors are widely used for the analysis of electron affine substances such as pesticides or chlorofluorocarbons. With detection limits in the low pptv range, electron capture detectors are the most sensitive detectors available for such compounds. Based on their operating principle, they require free electrons at atmospheric pressure, which are usually generated by a β- decay. However, the use of radioactive materials leads to regulatory restrictions regarding purchase, operation, and disposal. Here, we present a novel electron capture detector based on a non-radioactive electron source that shows similar detection limits compared to radioactive detectors but that is not subject to these limitations and offers further advantages such as adjustable electron densities and energies. In this work we show first experimental results using 1,1,2-trichloroethane and sevoflurane, and investigate the effect of several operating parameters on the analytical performance of this new non-radioactive electron capture detector (ECD).
UR - http://www.scopus.com/inward/record.url?scp=85038409923&partnerID=8YFLogxK
U2 - b10.5194/jsss-6-381-2017
DO - b10.5194/jsss-6-381-2017
M3 - Article
AN - SCOPUS:85038409923
VL - 6
SP - 381
EP - 387
JO - Journal of Sensors and Sensor Systems
JF - Journal of Sensors and Sensor Systems
SN - 2194-8771
IS - 2
ER -