Efficient Synthesis of Dimethyl Ether from Methanol in a Bifunctional Zeolite Membrane Reactor

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autoren

  • Chen Zhou
  • Nanyi Wang
  • Yanan Qian
  • Xiaoxing Liu
  • Jürgen Caro
  • Aisheng Huang

Organisationseinheiten

Externe Organisationen

  • Chinese Academy of Sciences (CAS)
  • CAS - Institute of Process Engineering
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)12678-12682
Seitenumfang5
FachzeitschriftAngewandte Chemie - International Edition
Jahrgang55
Ausgabenummer41
Frühes Online-Datum27 Sept. 2016
PublikationsstatusElektronisch veröffentlicht (E-Pub) - 27 Sept. 2016

Abstract

A sandwich FAU–LTA zeolite dual-layer membrane has been developed and used as a catalytic membrane reactor for the synthesis of dimethyl ether (DME). In the top H-FAU layer with mild acidity, methanol is dehydrated to DME. The other reaction product, water, is removed in situ through a hydrophilic Na-LTA layer, which is located between the porous alumina support and the H-FAU top layer. The combination of mild acidity with the continuous removal of water results in high methanol conversion (90.9 % at 310 °C) and essentially 100 % DME selectivity. Furthermore, owing to the selective and continuous removal of water through the Na-LTA membrane, catalyst deactivation can be effectively suppressed.

ASJC Scopus Sachgebiete

Zitieren

Efficient Synthesis of Dimethyl Ether from Methanol in a Bifunctional Zeolite Membrane Reactor. / Zhou, Chen; Wang, Nanyi; Qian, Yanan et al.
in: Angewandte Chemie - International Edition, Jahrgang 55, Nr. 41, 27.09.2016, S. 12678-12682.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Zhou, C., Wang, N., Qian, Y., Liu, X., Caro, J., & Huang, A. (2016). Efficient Synthesis of Dimethyl Ether from Methanol in a Bifunctional Zeolite Membrane Reactor. Angewandte Chemie - International Edition, 55(41), 12678-12682. Vorabveröffentlichung online. https://doi.org/10.1002/anie.201604753
Zhou C, Wang N, Qian Y, Liu X, Caro J, Huang A. Efficient Synthesis of Dimethyl Ether from Methanol in a Bifunctional Zeolite Membrane Reactor. Angewandte Chemie - International Edition. 2016 Sep 27;55(41):12678-12682. Epub 2016 Sep 27. doi: 10.1002/anie.201604753
Zhou, Chen ; Wang, Nanyi ; Qian, Yanan et al. / Efficient Synthesis of Dimethyl Ether from Methanol in a Bifunctional Zeolite Membrane Reactor. in: Angewandte Chemie - International Edition. 2016 ; Jahrgang 55, Nr. 41. S. 12678-12682.
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abstract = "A sandwich FAU–LTA zeolite dual-layer membrane has been developed and used as a catalytic membrane reactor for the synthesis of dimethyl ether (DME). In the top H-FAU layer with mild acidity, methanol is dehydrated to DME. The other reaction product, water, is removed in situ through a hydrophilic Na-LTA layer, which is located between the porous alumina support and the H-FAU top layer. The combination of mild acidity with the continuous removal of water results in high methanol conversion (90.9 % at 310 °C) and essentially 100 % DME selectivity. Furthermore, owing to the selective and continuous removal of water through the Na-LTA membrane, catalyst deactivation can be effectively suppressed.",
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T1 - Efficient Synthesis of Dimethyl Ether from Methanol in a Bifunctional Zeolite Membrane Reactor

AU - Zhou, Chen

AU - Wang, Nanyi

AU - Qian, Yanan

AU - Liu, Xiaoxing

AU - Caro, Jürgen

AU - Huang, Aisheng

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AB - A sandwich FAU–LTA zeolite dual-layer membrane has been developed and used as a catalytic membrane reactor for the synthesis of dimethyl ether (DME). In the top H-FAU layer with mild acidity, methanol is dehydrated to DME. The other reaction product, water, is removed in situ through a hydrophilic Na-LTA layer, which is located between the porous alumina support and the H-FAU top layer. The combination of mild acidity with the continuous removal of water results in high methanol conversion (90.9 % at 310 °C) and essentially 100 % DME selectivity. Furthermore, owing to the selective and continuous removal of water through the Na-LTA membrane, catalyst deactivation can be effectively suppressed.

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