Effect of oscillating magnetic fields on freezing of a colloidal dispersion of superparamagnetic nanoparticles

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Laura Otero
  • Antonio C. Rodríguez
  • Irene Morales
  • Rocío Costo
  • Patricia de la Presa
  • Pedro D. Sanz

Externe Organisationen

  • Spanish National Research Council (CSIC)
  • Complutense Universität Madrid (UCM)
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Aufsatznummer111440
Seitenumfang8
FachzeitschriftJournal of food engineering
Jahrgang347
Frühes Online-Datum6 Feb. 2023
PublikationsstatusVeröffentlicht - Juni 2023
Extern publiziertJa

Abstract

Several studies suggest that single-domain biogenic magnetic nanoparticles could play a major role on the effectiveness of oscillating magnetic fields (OMFs) in improving food freezing. To evaluate the potential role of superparamagnetic biogenic particles, we performed freezing experiments in a colloidal dispersion of <10-nm maghemite nanoparticles (MNPs) subjected or not to a 31.3-mT OMF at 50 Hz. Our results show that, at our experimental conditions, Néel mechanism governs the alignment of magnetic dipole moments and, therefore, no significant MNPs rotation, able to disturb the ordering of water molecules, should be expected during OMF experiments. Accordingly, no effects of the applied OMF were observed either on supercooling, ice nucleation, or on freezing kinetics even though heat removal was slightly increased during the precooling step. These results suggest that weak OMFs usually applied in commercial freezers should not produce any significant effect on superparamagnetic nanoparticles present in food that could improve the freezing process.

ASJC Scopus Sachgebiete

Zitieren

Effect of oscillating magnetic fields on freezing of a colloidal dispersion of superparamagnetic nanoparticles. / Otero, Laura; Rodríguez, Antonio C.; Morales, Irene et al.
in: Journal of food engineering, Jahrgang 347, 111440, 06.2023.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Otero L, Rodríguez AC, Morales I, Costo R, Presa PDL, Sanz PD. Effect of oscillating magnetic fields on freezing of a colloidal dispersion of superparamagnetic nanoparticles. Journal of food engineering. 2023 Jun;347:111440. Epub 2023 Feb 6. doi: 10.1016/j.jfoodeng.2023.111440
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abstract = "Several studies suggest that single-domain biogenic magnetic nanoparticles could play a major role on the effectiveness of oscillating magnetic fields (OMFs) in improving food freezing. To evaluate the potential role of superparamagnetic biogenic particles, we performed freezing experiments in a colloidal dispersion of <10-nm maghemite nanoparticles (MNPs) subjected or not to a 31.3-mT OMF at 50 Hz. Our results show that, at our experimental conditions, N{\'e}el mechanism governs the alignment of magnetic dipole moments and, therefore, no significant MNPs rotation, able to disturb the ordering of water molecules, should be expected during OMF experiments. Accordingly, no effects of the applied OMF were observed either on supercooling, ice nucleation, or on freezing kinetics even though heat removal was slightly increased during the precooling step. These results suggest that weak OMFs usually applied in commercial freezers should not produce any significant effect on superparamagnetic nanoparticles present in food that could improve the freezing process.",
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AU - Otero, Laura

AU - Rodríguez, Antonio C.

AU - Morales, Irene

AU - Costo, Rocío

AU - Presa, Patricia de la

AU - Sanz, Pedro D.

N1 - Publisher Copyright: © 2023 The Authors

PY - 2023/6

Y1 - 2023/6

N2 - Several studies suggest that single-domain biogenic magnetic nanoparticles could play a major role on the effectiveness of oscillating magnetic fields (OMFs) in improving food freezing. To evaluate the potential role of superparamagnetic biogenic particles, we performed freezing experiments in a colloidal dispersion of <10-nm maghemite nanoparticles (MNPs) subjected or not to a 31.3-mT OMF at 50 Hz. Our results show that, at our experimental conditions, Néel mechanism governs the alignment of magnetic dipole moments and, therefore, no significant MNPs rotation, able to disturb the ordering of water molecules, should be expected during OMF experiments. Accordingly, no effects of the applied OMF were observed either on supercooling, ice nucleation, or on freezing kinetics even though heat removal was slightly increased during the precooling step. These results suggest that weak OMFs usually applied in commercial freezers should not produce any significant effect on superparamagnetic nanoparticles present in food that could improve the freezing process.

AB - Several studies suggest that single-domain biogenic magnetic nanoparticles could play a major role on the effectiveness of oscillating magnetic fields (OMFs) in improving food freezing. To evaluate the potential role of superparamagnetic biogenic particles, we performed freezing experiments in a colloidal dispersion of <10-nm maghemite nanoparticles (MNPs) subjected or not to a 31.3-mT OMF at 50 Hz. Our results show that, at our experimental conditions, Néel mechanism governs the alignment of magnetic dipole moments and, therefore, no significant MNPs rotation, able to disturb the ordering of water molecules, should be expected during OMF experiments. Accordingly, no effects of the applied OMF were observed either on supercooling, ice nucleation, or on freezing kinetics even though heat removal was slightly increased during the precooling step. These results suggest that weak OMFs usually applied in commercial freezers should not produce any significant effect on superparamagnetic nanoparticles present in food that could improve the freezing process.

KW - Freezing

KW - Freezing kinetics

KW - Oscillating magnetic fields

KW - Supercooling

KW - Superparamagnetic nanoparticles

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