TY - JOUR

T1 - Effect of flexoelectricity on a bilayer molybdenum disulfide Schottky contact

AU - Sun, Liang

AU - Javvaji, B.

AU - Zhang, Chunli

AU - Zhuang, Xiaoying

AU - Chen, Weiqiu

N1 - Funding Information: This work was supported by the Natural Science Foundation of Zhejiang province, China (No. LR21A020002 ), the National Natural Science Foundation of China (Nos. 12172326, 11972139 , and 12192210 ), the National Key Research and Development Program of China (Nos. 2020YFA0711700 and 2020YFA0711701 ).

PY - 2022/11

Y1 - 2022/11

N2 - Molybdenum disulfide (MoS2), as a representative two-dimensional material, has distinctive physical and mechanical properties, especially in a bilayer form. Here, we conduct a study on the effect of out-of-plane flexoelectricity on a fabricated bilayer MoS2 Schottky contact via the Conductive Atomic Force Microscope (CAFM). The induced polarization in the sample under the tip force, which is entirely from the flexoelectric mechanism due to the absence of out-of-plane piezoelectricity in terms of the molybdenum-to-sulfur bond symmetry, changes the barrier height of the formed Schottky contact between the bilayer MoS2 and Au electrode. According to the Hertzian contact theory and the modified current equation of the classical thermionic emission theory, the relationship between the strain gradient and the effective barrier height ϕBp is quantitatively presented. The out-of-plane flexoelectric coefficients of the bilayer MoS2 are thus evaluated as f3333=0.4758 nC/m and f3113=f3223=0.2867 nC/m.

AB - Molybdenum disulfide (MoS2), as a representative two-dimensional material, has distinctive physical and mechanical properties, especially in a bilayer form. Here, we conduct a study on the effect of out-of-plane flexoelectricity on a fabricated bilayer MoS2 Schottky contact via the Conductive Atomic Force Microscope (CAFM). The induced polarization in the sample under the tip force, which is entirely from the flexoelectric mechanism due to the absence of out-of-plane piezoelectricity in terms of the molybdenum-to-sulfur bond symmetry, changes the barrier height of the formed Schottky contact between the bilayer MoS2 and Au electrode. According to the Hertzian contact theory and the modified current equation of the classical thermionic emission theory, the relationship between the strain gradient and the effective barrier height ϕBp is quantitatively presented. The out-of-plane flexoelectric coefficients of the bilayer MoS2 are thus evaluated as f3333=0.4758 nC/m and f3113=f3223=0.2867 nC/m.

KW - Bilayer

KW - Conductive Atomic Force Microscope (CAFM)

KW - Flexoelectric coefficient

KW - Flexoelectricity

KW - Molybdenum disulfide

UR - http://www.scopus.com/inward/record.url?scp=85136126784&partnerID=8YFLogxK

U2 - 10.1016/j.nanoen.2022.107701

DO - 10.1016/j.nanoen.2022.107701

M3 - Article

AN - SCOPUS:85136126784

VL - 102

JO - NANO ENERGY

JF - NANO ENERGY

SN - 2211-2855

M1 - 107701

ER -