Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Autoren

  • F. Jirasit
  • C. H. Rüscher
  • L. Lohaus
  • P. Chindaprasirt

Externe Organisationen

  • Rajamangala University of Technology Lanna (RMUTL)
  • Khon Kaen University
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Titel des SammelwerksDevelopments in Strategic Ceramic Materials II
UntertitelCeramic Engineering and Science
Herausgeber/-innenWaltraud M. Kriven, Yanchun Zhou, Jingyang Wang, Dongming Zhu, Gustavo Costa
Herausgeber (Verlag)American Ceramic Society
Seiten3-12
Seitenumfang10
Band37
Auflage7
ISBN (elektronisch)9781119321811
ISBN (Print)9781119040439
PublikationsstatusVeröffentlicht - 30 Jan. 2017
VeranstaltungDevelopments in Strategic Ceramic Materials II - 40th International Conference on Advanced Ceramics and Composites, ICACC 2016 - Daytona Beach, USA / Vereinigte Staaten
Dauer: 24 Jan. 201629 Jan. 2016

Publikationsreihe

NameCeramic Engineering and Science Proceedings
Nummer7
Band37
ISSN (Print)0196-6219

Abstract

The durability performance of Alkali-Activated Cements (AAC) i.e., metakaolin (AAMK), slag (AAH), fly ash (AAB), and their hybrids (AAMK/H, AAMK/B) were carried out by a carbonation test and degradation test in sulfuric acid pH 0.5. The effect of carbonation was followed by IR absorption spectroscopy, KBr method. Ordinary Portland Cement (OPC), modified-OPC, and AAC were monitored for 11 weeks. Series of AAMK, AAH, AAB, and their hybrids were prepared using 2 types of alkaline activator (K0.5 and K0.64) and their deterioration were monitored for 9 weeks. Any accelerated carbonation could be ruled out in the case of AAMK, while it occurred the more the higher the CaO content of the raw material. In those materials carbonation occurred with the possible formation of vaterite which split in the IR bands at about 1420 and 1490 cm-1 before exposure. Further reaction was detected by increasing the intensity of vaterite phase after being exposed to CO2 of 3 vol%. For the sulfuric acid, the AAC revealed much better compared to OPC. A comparison between 2 types of alkaline activator revealed that higher alkaline content yielded more deterioration. As compared between sources of starting materials, AAB tended to resist acid attack better than did AAMK. However, the AAB showed significant formation of cracks. The results are also discussed with respect to their long term mechanical properties followed over 5 years.

ASJC Scopus Sachgebiete

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Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids. / Jirasit, F.; Rüscher, C. H.; Lohaus, L. et al.
Developments in Strategic Ceramic Materials II: Ceramic Engineering and Science. Hrsg. / Waltraud M. Kriven; Yanchun Zhou; Jingyang Wang; Dongming Zhu; Gustavo Costa. Band 37 7. Aufl. American Ceramic Society, 2017. S. 3-12 (Ceramic Engineering and Science Proceedings; Band 37, Nr. 7).

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Jirasit, F, Rüscher, CH, Lohaus, L & Chindaprasirt, P 2017, Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids. in WM Kriven, Y Zhou, J Wang, D Zhu & G Costa (Hrsg.), Developments in Strategic Ceramic Materials II: Ceramic Engineering and Science. 7 Aufl., Bd. 37, Ceramic Engineering and Science Proceedings, Nr. 7, Bd. 37, American Ceramic Society, S. 3-12, Developments in Strategic Ceramic Materials II - 40th International Conference on Advanced Ceramics and Composites, ICACC 2016, Daytona Beach, USA / Vereinigte Staaten, 24 Jan. 2016. https://doi.org/10.1002/9781119321811.ch1
Jirasit, F., Rüscher, C. H., Lohaus, L., & Chindaprasirt, P. (2017). Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids. In W. M. Kriven, Y. Zhou, J. Wang, D. Zhu, & G. Costa (Hrsg.), Developments in Strategic Ceramic Materials II: Ceramic Engineering and Science (7 Aufl., Band 37, S. 3-12). (Ceramic Engineering and Science Proceedings; Band 37, Nr. 7). American Ceramic Society. https://doi.org/10.1002/9781119321811.ch1
Jirasit F, Rüscher CH, Lohaus L, Chindaprasirt P. Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids. in Kriven WM, Zhou Y, Wang J, Zhu D, Costa G, Hrsg., Developments in Strategic Ceramic Materials II: Ceramic Engineering and Science. 7 Aufl. Band 37. American Ceramic Society. 2017. S. 3-12. (Ceramic Engineering and Science Proceedings; 7). doi: 10.1002/9781119321811.ch1
Jirasit, F. ; Rüscher, C. H. ; Lohaus, L. et al. / Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids. Developments in Strategic Ceramic Materials II: Ceramic Engineering and Science. Hrsg. / Waltraud M. Kriven ; Yanchun Zhou ; Jingyang Wang ; Dongming Zhu ; Gustavo Costa. Band 37 7. Aufl. American Ceramic Society, 2017. S. 3-12 (Ceramic Engineering and Science Proceedings; 7).
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title = "Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids",
abstract = "The durability performance of Alkali-Activated Cements (AAC) i.e., metakaolin (AAMK), slag (AAH), fly ash (AAB), and their hybrids (AAMK/H, AAMK/B) were carried out by a carbonation test and degradation test in sulfuric acid pH 0.5. The effect of carbonation was followed by IR absorption spectroscopy, KBr method. Ordinary Portland Cement (OPC), modified-OPC, and AAC were monitored for 11 weeks. Series of AAMK, AAH, AAB, and their hybrids were prepared using 2 types of alkaline activator (K0.5 and K0.64) and their deterioration were monitored for 9 weeks. Any accelerated carbonation could be ruled out in the case of AAMK, while it occurred the more the higher the CaO content of the raw material. In those materials carbonation occurred with the possible formation of vaterite which split in the IR bands at about 1420 and 1490 cm-1 before exposure. Further reaction was detected by increasing the intensity of vaterite phase after being exposed to CO2 of 3 vol%. For the sulfuric acid, the AAC revealed much better compared to OPC. A comparison between 2 types of alkaline activator revealed that higher alkaline content yielded more deterioration. As compared between sources of starting materials, AAB tended to resist acid attack better than did AAMK. However, the AAB showed significant formation of cracks. The results are also discussed with respect to their long term mechanical properties followed over 5 years.",
author = "F. Jirasit and R{\"u}scher, {C. H.} and L. Lohaus and P. Chindaprasirt",
note = "Funding information: FJ is deeply indebted to Prof. Joseph Davidovits for his valuable discussions at the beginning of this research. FJ also thanks to Rajamangala University of Technology Lanna (RMUTL), Thailand, for supporting her stay abroad at Department for Building Materials, and Department of Mineralogy, both at University of Hannover, Germany. Special thanks to German Academic Exchange Service (DAAD) for funding the scholarship {\textquoteleft}Research Stays for University Academics and Scientists, 2015{\textquoteright} and also the travel grant by Leibniz Universit{\"a}t Hannover for my research visit to the Research Centre for Solid State Chemistry and New Materials (ZFM) at Leibniz Universit{\"a}t Hannover in June and July 2015. The University of Hannover is thanked for ACKNOWLEDGEMENTS FJ is deeply indebted to Prof. Joseph Davidovits for his valuable discussions at the beginning of this research. FJ also thanks to Rajamangala University of Technology Lanna (RMUTL), Thailand, for supporting her stay abroad at Department for Building Materials, and Department of Mineralogy, both at University of Hannover, Germany. Special thanks to German Academic Exchange Service (DAAD) for funding the scholarship {\textquoteleft}Research Stays for University Academics and Scientists, 2015{\textquoteright} and also the travel grant by Leibniz Universit{\"a}t Hannover for my research visit to the Research Centre for Solid State Chemistry and New Materials (ZFM) at Leibniz Universit{\"a}t Hannover in June and July 2015. The University of Hannover is thanked for; Developments in Strategic Ceramic Materials II - 40th International Conference on Advanced Ceramics and Composites, ICACC 2016 ; Conference date: 24-01-2016 Through 29-01-2016",
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editor = "Kriven, {Waltraud M.} and Yanchun Zhou and Jingyang Wang and Dongming Zhu and Gustavo Costa",
booktitle = "Developments in Strategic Ceramic Materials II",
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Download

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T1 - Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids

AU - Jirasit, F.

AU - Rüscher, C. H.

AU - Lohaus, L.

AU - Chindaprasirt, P.

N1 - Funding information: FJ is deeply indebted to Prof. Joseph Davidovits for his valuable discussions at the beginning of this research. FJ also thanks to Rajamangala University of Technology Lanna (RMUTL), Thailand, for supporting her stay abroad at Department for Building Materials, and Department of Mineralogy, both at University of Hannover, Germany. Special thanks to German Academic Exchange Service (DAAD) for funding the scholarship ‘Research Stays for University Academics and Scientists, 2015’ and also the travel grant by Leibniz Universität Hannover for my research visit to the Research Centre for Solid State Chemistry and New Materials (ZFM) at Leibniz Universität Hannover in June and July 2015. The University of Hannover is thanked for ACKNOWLEDGEMENTS FJ is deeply indebted to Prof. Joseph Davidovits for his valuable discussions at the beginning of this research. FJ also thanks to Rajamangala University of Technology Lanna (RMUTL), Thailand, for supporting her stay abroad at Department for Building Materials, and Department of Mineralogy, both at University of Hannover, Germany. Special thanks to German Academic Exchange Service (DAAD) for funding the scholarship ‘Research Stays for University Academics and Scientists, 2015’ and also the travel grant by Leibniz Universität Hannover for my research visit to the Research Centre for Solid State Chemistry and New Materials (ZFM) at Leibniz Universität Hannover in June and July 2015. The University of Hannover is thanked for

PY - 2017/1/30

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N2 - The durability performance of Alkali-Activated Cements (AAC) i.e., metakaolin (AAMK), slag (AAH), fly ash (AAB), and their hybrids (AAMK/H, AAMK/B) were carried out by a carbonation test and degradation test in sulfuric acid pH 0.5. The effect of carbonation was followed by IR absorption spectroscopy, KBr method. Ordinary Portland Cement (OPC), modified-OPC, and AAC were monitored for 11 weeks. Series of AAMK, AAH, AAB, and their hybrids were prepared using 2 types of alkaline activator (K0.5 and K0.64) and their deterioration were monitored for 9 weeks. Any accelerated carbonation could be ruled out in the case of AAMK, while it occurred the more the higher the CaO content of the raw material. In those materials carbonation occurred with the possible formation of vaterite which split in the IR bands at about 1420 and 1490 cm-1 before exposure. Further reaction was detected by increasing the intensity of vaterite phase after being exposed to CO2 of 3 vol%. For the sulfuric acid, the AAC revealed much better compared to OPC. A comparison between 2 types of alkaline activator revealed that higher alkaline content yielded more deterioration. As compared between sources of starting materials, AAB tended to resist acid attack better than did AAMK. However, the AAB showed significant formation of cracks. The results are also discussed with respect to their long term mechanical properties followed over 5 years.

AB - The durability performance of Alkali-Activated Cements (AAC) i.e., metakaolin (AAMK), slag (AAH), fly ash (AAB), and their hybrids (AAMK/H, AAMK/B) were carried out by a carbonation test and degradation test in sulfuric acid pH 0.5. The effect of carbonation was followed by IR absorption spectroscopy, KBr method. Ordinary Portland Cement (OPC), modified-OPC, and AAC were monitored for 11 weeks. Series of AAMK, AAH, AAB, and their hybrids were prepared using 2 types of alkaline activator (K0.5 and K0.64) and their deterioration were monitored for 9 weeks. Any accelerated carbonation could be ruled out in the case of AAMK, while it occurred the more the higher the CaO content of the raw material. In those materials carbonation occurred with the possible formation of vaterite which split in the IR bands at about 1420 and 1490 cm-1 before exposure. Further reaction was detected by increasing the intensity of vaterite phase after being exposed to CO2 of 3 vol%. For the sulfuric acid, the AAC revealed much better compared to OPC. A comparison between 2 types of alkaline activator revealed that higher alkaline content yielded more deterioration. As compared between sources of starting materials, AAB tended to resist acid attack better than did AAMK. However, the AAB showed significant formation of cracks. The results are also discussed with respect to their long term mechanical properties followed over 5 years.

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U2 - 10.1002/9781119321811.ch1

DO - 10.1002/9781119321811.ch1

M3 - Conference contribution

AN - SCOPUS:85044274868

SN - 9781119040439

VL - 37

T3 - Ceramic Engineering and Science Proceedings

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EP - 12

BT - Developments in Strategic Ceramic Materials II

A2 - Kriven, Waltraud M.

A2 - Zhou, Yanchun

A2 - Wang, Jingyang

A2 - Zhu, Dongming

A2 - Costa, Gustavo

PB - American Ceramic Society

T2 - Developments in Strategic Ceramic Materials II - 40th International Conference on Advanced Ceramics and Composites, ICACC 2016

Y2 - 24 January 2016 through 29 January 2016

ER -