Disentangling the puzzle of hydrogen bonding in vitamin C

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autorschaft

  • Isabel Peña
  • Adam M. Daly
  • Carlos Cabezas
  • Santiago Mata
  • Celina Bermúdez
  • Amaya Niño
  • Juan C. López
  • Jens Uwe Grabow
  • José L. Alonso

Organisationseinheiten

Externe Organisationen

  • Universidad de Valladolid
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)65-69
Seitenumfang5
FachzeitschriftJournal of Physical Chemistry Letters
Jahrgang4
Ausgabenummer1
PublikationsstatusVeröffentlicht - 3 Jan. 2013

Abstract

Fast-passage Fourier transform microwave spectroscopy in combination with a laser ablation source has been successfully applied to probe vitamin C (l-ascorbic acid) in the gas phase. Its ethyldiol side chain and two hydroxyl groups around the γ-lactone ring provide five internal rotation axes, enabling vitamin C to assume a wide variety of nonplanar 3D cooperative hydrogen bond networks that can also include the keto and ether functions. The rotational constants extracted from the analysis of the spectrum unequivocally identify the existence of three dominant conformers stabilized by different intramolecular hydrogen bonding motifs forming five-, six-, or seven-membered rings.

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Disentangling the puzzle of hydrogen bonding in vitamin C. / Peña, Isabel; Daly, Adam M.; Cabezas, Carlos et al.
in: Journal of Physical Chemistry Letters, Jahrgang 4, Nr. 1, 03.01.2013, S. 65-69.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Peña, I, Daly, AM, Cabezas, C, Mata, S, Bermúdez, C, Niño, A, López, JC, Grabow, JU & Alonso, JL 2013, 'Disentangling the puzzle of hydrogen bonding in vitamin C', Journal of Physical Chemistry Letters, Jg. 4, Nr. 1, S. 65-69. https://doi.org/10.1021/jz301947g
Peña, I., Daly, A. M., Cabezas, C., Mata, S., Bermúdez, C., Niño, A., López, J. C., Grabow, J. U., & Alonso, J. L. (2013). Disentangling the puzzle of hydrogen bonding in vitamin C. Journal of Physical Chemistry Letters, 4(1), 65-69. https://doi.org/10.1021/jz301947g
Peña I, Daly AM, Cabezas C, Mata S, Bermúdez C, Niño A et al. Disentangling the puzzle of hydrogen bonding in vitamin C. Journal of Physical Chemistry Letters. 2013 Jan 3;4(1):65-69. doi: 10.1021/jz301947g
Peña, Isabel ; Daly, Adam M. ; Cabezas, Carlos et al. / Disentangling the puzzle of hydrogen bonding in vitamin C. in: Journal of Physical Chemistry Letters. 2013 ; Jahrgang 4, Nr. 1. S. 65-69.
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AU - Mata, Santiago

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