Direct grafting-from of PEDOT from a photoreactive Zr-based MOF - a novel route to electrically conductive composite materials

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Alexander Mohmeyer
  • Andreas Schaate
  • Bastian Hoppe
  • Hendrik A. Schulze
  • Thea Heinemeyer
  • Peter Behrens

Organisationseinheiten

Externe Organisationen

  • Exzellenzcluster Hearing4all
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Details

OriginalspracheEnglisch
Seiten (von - bis)3367-3370
Seitenumfang4
FachzeitschriftChemical communications
Jahrgang55
Ausgabenummer23
Frühes Online-Datum26 Feb. 2019
PublikationsstatusVeröffentlicht - 21 März 2019

Abstract

The postsynthetic potential of the two-dimensional metal-organic framework Zr-bzpdc-MOF which is based on the photoreactive molecule benzophenone-4,4′-dicarboxylic acid (H2bzpdc) is used here to selectively functionalize the MOF surface. We report the direct radical-induced oxidative grafting-from polymerization of the precursor EDOT on Zr-bzpdc-MOF, leading to an electrically conductive composite material and opening the road to a variety of applications.

ASJC Scopus Sachgebiete

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Direct grafting-from of PEDOT from a photoreactive Zr-based MOF - a novel route to electrically conductive composite materials. / Mohmeyer, Alexander; Schaate, Andreas; Hoppe, Bastian et al.
in: Chemical communications, Jahrgang 55, Nr. 23, 21.03.2019, S. 3367-3370.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Mohmeyer A, Schaate A, Hoppe B, Schulze HA, Heinemeyer T, Behrens P. Direct grafting-from of PEDOT from a photoreactive Zr-based MOF - a novel route to electrically conductive composite materials. Chemical communications. 2019 Mär 21;55(23):3367-3370. Epub 2019 Feb 26. doi: 10.1039/c8cc10298h, 10.15488/4712
Mohmeyer, Alexander ; Schaate, Andreas ; Hoppe, Bastian et al. / Direct grafting-from of PEDOT from a photoreactive Zr-based MOF - a novel route to electrically conductive composite materials. in: Chemical communications. 2019 ; Jahrgang 55, Nr. 23. S. 3367-3370.
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AU - Schaate, Andreas

AU - Hoppe, Bastian

AU - Schulze, Hendrik A.

AU - Heinemeyer, Thea

AU - Behrens, Peter

N1 - Funding information: This work was partially funded by the DFG EXC 1077/1 ‘‘Hearing4all’’. We thank Katharina Nolte for thermogravimetric analysis and Claudia Schulze for elemental analysis. Also we thank the Institute for Organic Chemistry (Leibniz University Hannover) for performing NMR spectroscopy measurements.

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